Citation: Wang Wen-He, Gao Qiang, Li Ai-Lin, Jia Yan-Yuan, Zhang Shi-Yu, Wang Jian-Hong, Zhang Ying-Hui, Bu Xian-He. A coordination compound featuring a supramolecular hydrogen-bonding network for proton conduction[J]. Chinese Chemical Letters, ;2018, 29(2): 336-338. doi: 10.1016/j.cclet.2017.08.033 shu

A coordination compound featuring a supramolecular hydrogen-bonding network for proton conduction

a.
Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China
b.
School of Materials Science and Engineering, TKL of Metal-and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Zhang Ying-Hui, zhangyhi@nankai.edu.cn Bu Xian-He, buxh@nankai.edu.cn
Received Date: 14 June 2017
Revised Date: 11 August 2017
Accepted Date: 15 August 2017
Available Online: 3 March 2017

Figures(3)

A new coordination compound[Mg(L)(H₂O)₅·H₂O] (NKU-109, H₂L=5-(4H-1, 2, 4-triazol-4-yl)benzene-1, 3-dicarboxylic acid) was solvothermally synthesized, featuring a supramolecular hydrogen-bonding network. A good proton conductivity of 5.87×10^-4 S/cm was recorded at 70℃ and a relative humidity of 75% in alternating current (AC) impedance experiment, which sheds a new light on the design of proton conduction materials based on coordination compounds.
- Coordination compound,
- Fuel cell,
- Hydrogen-bonding network,
- Supramolecular,
- Proton conductivity
1. [1]
  R.J. Brodd, M. Winter, Chem. Rev. 104(2004) 4245-4269. doi: 10.1021/cr020730k
2. [2]
  M.K. Song, H. Li, J. Li, et al., Adv. Mater. 26(2014) 1277-1282. doi: 10.1002/adma.v26.8
3. [3]
  S. Horike, D. Umeyama, S. Kitagawa, Acc. Chem. Res. 46(2013) 2376-2384. doi: 10.1021/ar300291s
4. [4]
  J.A. Hurd, R. Vaidhyanathan, V. Thangadurai, et al., Nat. Chem. 1(2009) 705-710. doi: 10.1038/nchem.402
5. [5]
  M. Yoon, K. Suh, S. Natarajan, K. Kim, Angew. Chem. Int. Ed. 52(2013) 2688-2700.
6. [6]
  S. Bureekaew, S. Horike, M. Higuchi, et al., Nat. Mater. 8(2009) 831-836.
7. [7]
  B. Wang, H. Yang, Y.B. Xie, et al., Chin. Chem. Lett. 27(2016) 502-506. doi: 10.1016/j.cclet.2015.12.034
8. [8]
  O. Alduhaish, B. Li, H. Arman, et al., Chin. Chem. Lett. 28(2017) 1653-1658. doi: 10.1016/j.cclet.2017.04.025
9. [9]
  O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, et al., Nature 423(2003) 705-714. doi: 10.1038/nature01650
10. [10]
  N.W. Ockwig, O. Delgado-friedrichs, M. O'Keeffe, O.M. Yaghi, Acc. Chem. Res. 38(2005) 176-182.
11. [11]
  A.L. Li, Q. Gao, J. Xu, X.H. Bu, Coord. Chem. Rev. 344(2017) 54-82.
12. [12]
  W.J. Phang, H. Jo, W.R. Lee, et al., Angew. Chem. Int. Ed. Engl. 54(2015) 5142-5146. doi: 10.1002/anie.v54.17
13. [13]
  X. Wang, X.Y. Duan, C.Y. Kong, M.L. Wei, J. Coord. Chem. 69(2016) 779-787.
14. [14]
  X. Wang, C.Y. Kong, J.J. Lai, M.L. Wei, J. Clust. Sci. 27(2016) 645-656. doi: 10.1007/s10876-015-0965-8
15. [15]
  W. Nbili, K. Kaabi, W. Ferenc, et al., J. Mol. Struct. 1130(2017) 114-121. doi: 10.1016/j.molstruc.2016.10.016
16. [16]
  A. Pangon, K. Tashiro, S. Chirachanchai, J. Phys. Chem. B 115(2011) 11359-11367. doi: 10.1021/jp205491w
17. [17]
  K. Pogorzelec-Glaser, A. Rachocki, P. Ławniczak, et al., CrystEngComm 15(2013) 1950-1959.
18. [18]
  Q. Gao, X.L. Wang, J. Xu, X.H. Bu, Chem. Eur. J. 22(2016) 9082-9086. doi: 10.1002/chem.201601233
19. [19]
  S.J. Liu, C. Cao, F. Yang, et al., Cryst. Growth Des. 16(2016) 166776-166780.
20. [20]
  F. Yang, H.L. Huang, X.Y. Wang, et al., Cryst. Growth Des. 15(2015) 5827-5833. doi: 10.1021/acs.cgd.5b01190
21. [21]
  Y.J. Sun, Y. Yan, Y.Y. Wang, et al., Chem. Commun. 45(2015) 9317-9319.
22. [22]
  P. Ramaswamy, N.E. Wong, G.K.H. Shimizu, Chem. Soc. Rev. 43(2014) 5913-5932. doi: 10.1039/C4CS00093E
1. [1]
  Hong-Jin Liao , Zhu Zhuo , Qing Li , Yoshihito Shiota , Jonathan P. Hill , Katsuhiko Ariga , Zi-Xiu Lu , Lu-Yao Liu , Zi-Ang Nan , Wei Wang , You-Gui Huang . A new class of crystalline X-ray induced photochromic materials assembled from anion-directed folding of a flexible cation. Chinese Chemical Letters, 2024, 35(8): 109052-. doi: 10.1016/j.cclet.2023.109052
2. [2]
  Zhikang Wu , Guoyong Dai , Qi Li , Zheyu Wei , Shi Ru , Jianda Li , Hongli Jia , Dejin Zang , Mirjana Čolović , Yongge Wei . POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. Chinese Chemical Letters, 2024, 35(8): 109061-. doi: 10.1016/j.cclet.2023.109061
3. [3]
  Qian Liu , Yi Shi , Kaiya Wang , Xiao-Yu Hu . Tailoring cascade hydrolysis and cyclization efficiency in confined spaces via spatial and electrostatic regulation. Chinese Chemical Letters, 2025, 36(12): 111462-. doi: 10.1016/j.cclet.2025.111462
4. [4]
  Jun Luo , Yanya Liu , Jianghuaxiong Zhu , Chengxiong Wang , Yunkun Zhao , Dong Yan , Jian Li , Lichao Jia . A proton-conducting solid oxide fuel cell for co-production of ethylene and power via ethane conversion. Chinese Chemical Letters, 2025, 36(7): 110171-. doi: 10.1016/j.cclet.2024.110171
5. [5]
  Shiqi Zhang , Heng Zhang , Aiwen Lei . 从物理化学的角度看化学能的利用. University Chemistry, 2025, 40(6): 310-315. doi: 10.12461/PKU.DXHX202408124
6. [6]
  Jiaqi Lin , Pupu Yang , Yimin Jiang , Shiqian Du , Dongcai Zhang , Gen Huang , Jinbo Wang , Jun Wang , Qie Liu , Miaoyu Li , Yujie Wu , Peng Long , Yangyang Zhou , Li Tao , Shuangyin Wang . Surface decoration prompting the decontamination of active sites in high-temperature proton exchange membrane fuel cells. Chinese Chemical Letters, 2024, 35(11): 109435-. doi: 10.1016/j.cclet.2023.109435
7. [7]
  Yuetong Gao , Tong Mu , Xinyue Hu , Yang Pang , Chengji Zhao . Facile synthesis of all-carbon fluorinated backbone polymers containing sulfide linkage as proton exchange membranes for fuel cells. Chinese Chemical Letters, 2025, 36(6): 110763-. doi: 10.1016/j.cclet.2024.110763
8. [8]
  Songtao Cai , Liuying Wu , Yuan Li , Soham Samanta , Jinying Wang , Bing Liu , Feihu Wu , Kaitao Lai , Yingchao Liu , Junle Qu , Zhigang Yang . Intermolecular hydrogen-bonding as a robust tool toward significantly improving the photothermal conversion efficiency of a NIR-II squaraine dye. Chinese Chemical Letters, 2024, 35(4): 108599-. doi: 10.1016/j.cclet.2023.108599
9. [9]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
10. [10]
  Qian Ren , Xue Dai , Ran Cen , Yang Luo , Mingyang Li , Ziyun Zhang , Qinghong Bai , Zhu Tao , Xin Xiao . A cucurbit[8]uril-based supramolecular phosphorescent assembly: Cell imaging and sensing of amino acids in aqueous solution. Chinese Chemical Letters, 2024, 35(12): 110022-. doi: 10.1016/j.cclet.2024.110022
11. [11]
  Shengyong Liu , Hui Li , Wei Zhang , Yan Zhang , Yan Dong , Wei Tian . Multiple host-guest and metal coordination interactions induce supramolecular assembly and structural transition. Chinese Chemical Letters, 2025, 36(6): 110465-. doi: 10.1016/j.cclet.2024.110465
12. [12]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
13. [13]
  Wenqing Deng , Fanfeng Deng , Ting Zhang , Junjie Lin , Liang Zhao , Gang Li , Yi Pan , Jiebin Yang . Continuous measurement of reactive ammonia in hydrogen fuel by online dilution module coupled with Fourier transform infrared spectrometer. Chinese Chemical Letters, 2025, 36(3): 110085-. doi: 10.1016/j.cclet.2024.110085
14. [14]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
15. [15]
  Xiangjun Zhang , Xiaodi Yang , Yan Wang , Zhongping Xu , Sisi Yi , Tao Guo , Yue Liao , Xiyu Tang , Jianxiang Zhang , Ruibing Wang . A supramolecular nanoprodrug for prevention of gallstone formation. Chinese Chemical Letters, 2025, 36(2): 109854-. doi: 10.1016/j.cclet.2024.109854
16. [16]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
17. [17]
  Gongxi Li , Jun Jin , Junxuan Tu , Haoguo Yue , Ying Wang , Xiaohui Jia , Weiyuan Yin , Zhenglin Han , Yuxuan Deng , Chunfeng Shi , Yonggang Zhen . Intrinsically stretchable polymer semiconductors synergistically constructed by hydrogen bonds and metal coordination. Chinese Chemical Letters, 2025, 36(12): 111716-. doi: 10.1016/j.cclet.2025.111716
18. [18]
  Rui Wang , Yang Liang , Julius Rebek Jr. , Yang Yu . Stabilization and detection of labile reaction intermediates in supramolecular containers. Chinese Chemical Letters, 2024, 35(6): 109228-. doi: 10.1016/j.cclet.2023.109228
19. [19]
  Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
20. [20]
  Xinguo Mao , Shuo Zhang , Qiang Shi , Hua Cheng , Leyong Wang . Macrocyclic host molecules: Rising as a promising supramolecular material. Chinese Chemical Letters, 2025, 36(6): 110950-. doi: 10.1016/j.cclet.2025.110950

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1162)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142