Citation: Cao Shi-Xuan, Wang Jia-Xi, He Zheng-Jie. Magnetic nanoparticles supported cinchona alkaloids for asymmetric Michael addition reaction of 1, 3-dicarbonyls and maleimides[J]. Chinese Chemical Letters, ;2018, 29(1): 201-204. doi: 10.1016/j.cclet.2017.06.022 shu

Magnetic nanoparticles supported cinchona alkaloids for asymmetric Michael addition reaction of 1, 3-dicarbonyls and maleimides

a.
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China
b.
The State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
c.
Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300071, China

Corresponding author: Wang Jia-Xi, wangjiaxi@hebut.edu.cn He Zheng-Jie, zhengjiehe@nankai.edu.cn
Received Date: 29 April 2017
Revised Date: 4 June 2017
Accepted Date: 22 June 2017
Available Online: 26 January 2017

Figures(3)

Magnetic nanoparticles Fe₃O₄@SiO₂ supported cinchona alkaloids (quinine and quinidine) were successfully synthesized as magnetically recoverable organocatalysts and characterized by FT-IR, XPS, SEM measurements, and elemental analysis. Their catalytic activity and stereoselectivity were preliminarily evaluated in the asymmetric Michael addition reaction of 1, 3-dicarbonyls and maleimides. The supported quinine catalyst exhibited good catalytic efficiency and modest to high enantioselectivity. The magnetic recoverability and recyclability of the catalyst were also examined.
- Magnetic nanoparticles,
- Cinchona alkaloids,
- Immobilization,
- Michael addition,
- Asymmetric catalysis
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