Citation: Lyu Jing-Hui, Hu Hua-Lei, Rui Jia-Yao, Zhang Qun-Feng, Cen Jie, Han Wen-Wen, Wang Qing-Tao, Chen Xiao-Kun, Pan Zhi-Yan, Li Xiao-Nian. Nitridation: A simple way to improve the catalytic performance of hierarchical porous ZSM-5 in benzene alkylation with methanol[J]. Chinese Chemical Letters, ;2017, 28(2): 482-486. doi: 10.1016/j.cclet.2016.10.025 shu

Nitridation: A simple way to improve the catalytic performance of hierarchical porous ZSM-5 in benzene alkylation with methanol

a.
Industrial Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou 310032, China
b.
Department of Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032, China

Corresponding author: Li Xiao-Nian, xnli@zjut.edu.cn
Received Date: 20 July 2016
Revised Date: 18 September 2016
Accepted Date: 22 September 2016
Available Online: 27 February 2016

Figures(8)

Nitrided hierarchical porous ZSM-5 was synthesized by nitridation of hierarchical porous ZSM-5 with flowing ammonia at elevated temperature. The samples were characterized by XRD, SEM, Nitrogen sorption isotherms, NH₃-TPD and Py-IR, and evaluated in alkylation of benzene and methanol. The result indicated that the high specific surface area of parent ZSM-5 was maintained, while the Brönsted acidity was effectively adjusted by nitridation. Moreover, the high suppression of ethylbenzene was observed on nitrided catalyst and this could be attributed to the decrease of Brönsted acidity which suppressed the methanol to olefins reactions.
- Nitridation,
- Hierarchical porous ZSM-5,
- Benzene alkylation with methanol,
- Ethylbenzene
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