Citation: Fu Ju, Tan Xiao-Hong, Li Yao-Hua, Song Xin-Jian. A nanosilica/exfoliated graphene composite film-modified electrode for sensitive detection of methyl parathion[J]. Chinese Chemical Letters, ;2016, 27(9): 1541-1546. doi: 10.1016/j.cclet.2016.07.007 shu

A nanosilica/exfoliated graphene composite film-modified electrode for sensitive detection of methyl parathion

Fu Ju ^a,b ,
Tan Xiao-Hong ^b ,
Li Yao-Hua ^b ,
Song Xin-Jian ^a,b,,

a.
Key Laboratory of Biologic Resources Protection and Utilization of Hubei Province, Hubei University for Nationalities, Enshi 445000, China
b.
School of Chemical and Environmental Engineering, Hubei University for Nationalities, Enshi 445000, China

Corresponding author: Song Xin-Jian, whxjsong@163.com
Received Date: 16 May 2016
Revised Date: 22 June 2016
Accepted Date: 4 July 2016
Available Online: 16 September 2016

Figures(7)

Graphene nanosheets (GS) were easily prepared through liquid-phase exfoliation of graphite powder in N, N-dimethylformamide (DMF) with the assistance of sodium citrate. Then, GS was coated onto a glassy carbon electrode (GCE) surface by drop to fabricate a GS/GCE nanointerface. Subsequently, by using tetraethylorthosilicate sol as precursor, nanosilica was electrochemically deposited onto the GS/GCE surface to produce a nanocomposite film electrode (nanosilica/GS/GCE). Electrochemical behaviors of methyl parathion (MP) on the nanosilica/GS/GCE surface were investigated thoroughly. It was found that the nanosilica/GS nanocomposites can improve the redox peak currents of MP significantly due to the synergetic effect. The oxidation peak current was linearly related to MP concentration in the range from 0.0005 μmol/L to 5.6 μmol/L. The detection limit was calculated to be 0.07 nmol/L (S/N=3). The developed method was used to determine MP in real samples. The recoveries were in the range from 95.4% to 104.2%, demonstrating satisfactory results.
- Exfoliated graphene,
- Nanosilica,
- Modified electrodes,
- Methyl parathion,
- Electrochemical sensor
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