Citation: Hai-Feng Li, Zhang Qin-Sheng, Pang Zeng-Bo, Tian Mi, Gao Ping, Wang Lai-Lai. Pd/TiN nanocomposite catalysts for selective hydrogenation of phenol and its derivatives[J]. Chinese Chemical Letters, ;2016, 27(9): 1500-1504. doi: 10.1016/j.cclet.2016.03.036 shu

Pd/TiN nanocomposite catalysts for selective hydrogenation of phenol and its derivatives

Hai-Feng Li ^a ,
Zhang Qin-Sheng ^a ,
Pang Zeng-Bo ^a,b ,
Tian Mi ^a,b ,
Gao Ping ^c,, ,
Wang Lai-Lai ^a,,

a.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
Graduate University of Chinese Academy of Sciences, Bejing 100039, China
c.
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Corresponding author: Gao Ping, gaoping@licp.cas.cn Wang Lai-Lai, wll@licp.cas.cn
Received Date: 3 February 2016
Revised Date: 9 March 2016
Accepted Date: 15 March 2016
Available Online: 1 September 2016

Figures(4)

Pd/TiN nanocomposite catalysts were fabricated for one-step selective hydrogenation of phenol to cyclohexanone successfully. High conversion of phenol (99%) and selectivity of cyclohexanone (98%) were obtained at 30℃ and 0.2 MPa H₂ for 12 h in the mixed solvents of H₂O and CH₂Cl₂. The Pd nanoparticles were stable in the reaction, and no aggregation was detected after four successive runs. The catalytic activity and selectivity depended on slightly the Pd particle sizes. The generality of the catalysts for this reaction was demonstrated by the selective hydrogenation of phenol derivatives, which showed that the catalyst was selective for the formation of cyclohexanone.
- Phenol,
- Hydrogenation,
- Cyclohexanone,
- TiN support,
- Pd/TiN catalysts
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