Citation: Wu Chaolumen, Liao Chen-Bo, Li Lei, Yang Jun. Ethylene sulfite based electrolyte for non-aqueous lithium oxygen batteries[J]. Chinese Chemical Letters, ;2016, 27(9): 1485-1489. doi: 10.1016/j.cclet.2016.03.023 shu

Ethylene sulfite based electrolyte for non-aqueous lithium oxygen batteries

Wu Chaolumen ^a ,
Liao Chen-Bo ^a ,
Li Lei ^a,, ,
Yang Jun ^b

a.
School of Chemistry and Chemical Engineering, Shanghai Key Lab of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University, Shanghai 200240, China
b.
Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Li Lei, lilei0323@sjtu.edu.cn
Received Date: 4 January 2016
Revised Date: 9 March 2016
Accepted Date: 14 March 2016
Available Online: 19 September 2016

Figures(5)

Non-aqueous lithium-oxygen (Li-O₂) batteries have been considered as the superior energy storage system due to their high-energy density, however, some challenges limit the practical application of Li-O₂ batteries. One of them is the lack of stable electrolyte. In this communication, a novel electrolyte with ethylene sulfite (ES) used as solvent for Li-O₂ batteries was reported. ES solvent showed low volatility and high electrochemical stability. Without a catalyst in the air-electrode of Li-O₂ batteries, the batteries showed high specific capacity, good round-trip efficiency and cycling stability.
- Lithium-oxygen batteries,
- Electrolyte,
- Ethylene sulfite,
- Cycling stability,
- Electrochemical stability
1. [1]
  Bruce P.G., Freunberger S.A., Hardwick L.J., Tarascon J.-M.. Li-O₂ and Li-S batteries with high energy storage[J]. Nat. Mater., 2012,11:19-29.
2. [2]
  Scrosati B., Hassoun J., Sun Y.-K.. Lithium-ion batteries. a look into the future[J]. Energy Environ. Sci., 2011,4:3287-3295. doi: 10.1039/c1ee01388b
3. [3]
  Lu J., Li L., Park J.-B.. Aprotic and aqueous Li-O₂ batteries[J]. Chem. Rev., 2014,114:5611-5640. doi: 10.1021/cr400573b
4. [4]
  Balaish M., Kraytsberg A., Ein-Eli Y.. A critical review on lithium-air battery electrolytes[J]. Phys. Chem. Chem. Phys., 2014,16:2801-2822. doi: 10.1039/c3cp54165g
5. [5]
  Ferrari S., Quartarone E., Tomasi C.. Investigation of ether-based ionic liquid electrolytes for lithium-O₂ batteries[J]. J. Electrochem. Soc., 2015,162:A3001-A3006. doi: 10.1149/2.0101511jes
6. [6]
  Das S., Højberg J., Knudsen K.B.. Instability of ionic liquid-based electrolytes in Li-O₂ batteries[J]. J. Phys. Chem. C, 2015,119:18084-18090. doi: 10.1021/acs.jpcc.5b04950
7. [7]
  Zhao G.Y., Zhang L., Wang B.Y., Sun K.N.. Cuprous oxide as cathode catalysts of lithium oxygen batteries[J]. Electrochim. Acta, 2015,184:117-123. doi: 10.1016/j.electacta.2015.10.059
8. [8]
  Jung H.G., Hassoun J., Park J.-B., Sun Y.-K., Scrosati B.. An improved high-performance lithium-air battery[J]. Nat. Chem., 2012,4:579-585. doi: 10.1038/nchem.1376
9. [9]
  Peng Z.Q., Freunberger S.A., Chen Y.H., Bruce P.G.. A reversible and higher-rate Li-O₂ battery[J]. Science, 2012,337:563-566. doi: 10.1126/science.1223985
10. [10]
  David G.K., Thomas P.B., Chibueze V.A.. Chemical instability of dimethyl sulfoxide in lithium-air batteries[J]. J. Phys. Chem. Lett., 2014,5:2850-2856. doi: 10.1021/jz5013824
11. [11]
  Wrodnigg G.H., Besenhard J.O., Winter M.. Ethylene sulfite as electrolyte additive for lithium-ion cells with graphitic anodes[J]. J. Electrochem. Soc., 1999,146:470-472. doi: 10.1149/1.1391630
12. [12]
  T. Yamahira, Y. Imamura, Japan Patent 08-096851, 1996.
13. [13]
  Amanchukwu C.V., Harding J.R., Yang S.-H., Hammond P.T.. Understanding the chemical stability of polymers for lithium-air batteries[J]. Chem. Mater., 2015,27:550-561. doi: 10.1021/cm5040003
14. [14]
  Sharon D., Afri M., Noked M.. Oxidation of dimethyl sulfoxide solutions by electrochemical reduction of oxygen[J]. J. Phys. Chem. Lett., 2013,4:3115-3119. doi: 10.1021/jz4017188
15. [15]
  Xu D., Wang Z.L., Xu J.J.. A stable sulfonebasedelectrolyteforhigh performance rechargeable Li-O₂ batteries[J]. Chem. Commun., 2012,48:11674-11676. doi: 10.1039/c2cc36815c
16. [16]
  Xu J.J., Wang Z.L., Xu D., Zhang L.L., Zhang X.B.. Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries[J]. Nat. Commun., 2013,42438.
1. [1]
  Zhe Wang , Li-Peng Hou , Qian-Kui Zhang , Nan Yao , Aibing Chen , Jia-Qi Huang , Xue-Qiang Zhang . High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries. Chinese Chemical Letters, 2024, 35(4): 108570-. doi: 10.1016/j.cclet.2023.108570
2. [2]
  Ruonan Yang , Jiajia Li , Dongmei Zhang , Xiuqi Zhang , Xia Li , Han Yu , Zhanhu Guo , Chuanxin Hou , Gang Lian , Feng Dang . Grain-refining Co_0.85Se@CNT cathode catalyst with promoted Li₂O₂ growth kinetics for lithium-oxygen batteries. Chinese Chemical Letters, 2024, 35(12): 109595-. doi: 10.1016/j.cclet.2024.109595
3. [3]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
4. [4]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
5. [5]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180
6. [6]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
7. [7]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
8. [8]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
9. [9]
  Jingyu Shi , Xiaofeng Wu , Yutong Chen , Yi Zhang , Xiangyan Hou , Ruike Lv , Junwei Liu , Mengpei Jiang , Keke Huang , Shouhua Feng . Structure factors dictate the ionic conductivity and chemical stability for cubic garnet-based solid-state electrolyte. Chinese Chemical Letters, 2025, 36(5): 109938-. doi: 10.1016/j.cclet.2024.109938
10. [10]
  Mengwen Wang , Qintao Sun , Yue Liu , Zhengan Yan , Qiyu Xu , Yuchen Wu , Tao Cheng . Impact of lithium nitrate additives on the solid electrolyte interphase in lithium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(2): 100203-100203. doi: 10.1016/j.cjsc.2023.100203
11. [11]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
12. [12]
  Qiyan Wu , Ruixin Zhou , Zhangyi Yao , Tanyuan Wang , Qing Li . Effective approaches for enhancing the stability of ruthenium-based electrocatalysts towards acidic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(10): 109416-. doi: 10.1016/j.cclet.2023.109416
13. [13]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
14. [14]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
15. [15]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
16. [16]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
17. [17]
  Haining Peng , Huijun Liu , Chengzong Li , Yingfu Li , Qizhi Chen , Tao Li . Diluent modified weakly solvating electrolyte for fast-charging high-voltage lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 109556-. doi: 10.1016/j.cclet.2024.109556
18. [18]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
19. [19]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
20. [20]
  Haiying Lu , Weijie Li . The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(11): 100334-100334. doi: 10.1016/j.cjsc.2024.100334

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(743)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142