Citation: Di Xiao-Xia, Zhao Jia, Yu Yi, Xu Xiao-Long, Gu Shan-Chuan, He Hai-Hua, Zhang Tong-Tong, Li Xiao-Nian. One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl₃ as efficient catalysts for acetylene hydrochlorination[J]. Chinese Chemical Letters, ;2016, 27(9): 1567-1571. doi: 10.1016/j.cclet.2016.03.004 shu

One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl₃ as efficient catalysts for acetylene hydrochlorination

Institute of Industrial Catalysis of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou310032, China

Corresponding author: Li Xiao-Nian, xnli@zjut.edu.cn
Received Date: 14 January 2016
Revised Date: 4 March 2016
Accepted Date: 14 March 2016
Available Online: 14 September 2016

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Commercialization of acetylene hydrochlorination using AuCl₃ catalysts has been impeded by its poor stability. We have been studying that nitrogen-modified Au/NAC catalyst delivered a stable performance which can improve acetylene hydrochlorination activity and has resistance to catalytic deactivation. Here we show that nitrogen and sulfur co-doped activated carbon supported AuCl₃ catalyst worked as efficient catalysts for the hydrochlorination of acetylene to vinyl chloride. Au/NSAC catalyst demonstrated high activity comparative to Au/AC catalyst. Furthermore, it also delivered stable performance within the selectivity of acetylene, reaching more than 99.5%, and there was only a 3.3% C₂H₂ conversion loss after running for 12 h under the reaction conditions of a temperature of 180℃ and a C₂H₂ hourly space velocity of 1480 h 1. The presence of the sulfur atoms may serve to immobilize/anchor the Au and also help prevent reduction and sintering of the Au and hence improve the catalytic activity and stability. The excellent catalytic performance of the Au/NSAC catalyst demonstrated its potential as an alternative to mercury chloride catalysts for acetylene hydrochlorination.
- Acetylene,
- Hydrochlorination,
- AuCl₃,
- Nitrogen and sulfur co-doped
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl3 as efficient catalysts for acetylene hydrochlorination

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通讯作者: 陈斌, bchen63@163.com

One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl₃ as efficient catalysts for acetylene hydrochlorination