Citation: Wei Xu, Cai-Feng Ding, Xin-Wen Wang, Xiao-Li Liu, Zhi-Dong Qiu. Two new triterpenoid saponins from notoginseng medicinal fungal substance[J]. Chinese Chemical Letters, ;2015, 26(10): 1298-1302. doi: 10.1016/j.cclet.2015.07.014 shu

Two new triterpenoid saponins from notoginseng medicinal fungal substance

1.
College of Pharmacy, Changchun University of Chinese Medicine, Changchun 130117, China

Corresponding author: Zhi-Dong Qiu,
Received Date: 14 April 2015
Available Online: 25 June 2015
Fund Project:

Two new triterpenoid saponins, named ginsenoside Rh₁₀ (1) and notoginsenoside ST-6 (2), were isolated from notoginseng medicinal fungal substance. Their structures were elucidated by a combination of 1D and 2D NMR, MS and chemical analysis.
- Notoginseng,
- Triterpenoid ginsenoside,
- Ginsenoside Rh₁₀,
- Notoginsenoside ST-6
1. [1]
  [1] B. Chen, H.L. Xu, X.B. Jia, Research progress and thought on processing of Panax notoginseng, Chin. Tradit. Herb. Drugs 44(2013) 482-487.
2. [2]
  [2] X.H. Wang, Q.D. Li, Q.E. Cao, New field for study of TCM through fermentation by microbe, Chin. Tradit. Herb. Drugs 32(2001) 267-268.
3. [3]
  [3] M. Górecki, A. Kamińska, P. Ruśkowska, A. Suszczyńska, J. Frelek, Dimolybdenum method for determination of the absolute configuration of vic-diols-foundations and developments, Pol. J. Chem. 80(2006) 523-534.
4. [4]
  [4] J. Frelek, A. Klimek, P. Ruskowska, Dinuclear transition metal complexes as auxiliary chromophores in chiroptical studies on bioactive compounds, Curr. Org. Chem. 7(2003) 1081-1104.
5. [5]
  [5] M. Górecki, E. Jabłońska, A. Kruszewska, et al., Practical method for the absolute configuration assignment of tert/tert 1,2-diols using their complexes with Mo₂(OAc)₄, J. Org. Chem. 72(2007) 2906-2916.
6. [6]
  [6] L. Di Bari, G. Pescitelli, C. Pratelli, D. Pini, P. Salvadori, Determination of absolute configuration of acyclic 1, 2-diols with Mo₂(OAc)₄. 1. Snatzke's method revisited, J. Org. Chem. 66(2001) 4819-4825.
7. [7]
  [7] M. Politi, N. De Tommasi, G. Pescitelli, et al., Structure and absolute configuration of new diterpenes from Lavandula multifida, J. Nat. Prod. 65(2002) 1742-1745.
8. [8]
  [8] J. Liu, Y.B. Liu, Y.K. Si, et al., New vernocuminosides from the stem barks of Vernonia cumingiana Benth, Steroids 74(2009) 51-61.
9. [9]
  [9] L.F. Han, K.J. Sakah, L.L. Liu, et al., Saponins from roots of Panax notoginseng, Chin. Herb. Med. 6(2014) 159-163.
10. [10]
  [10] B.H. Han, M.H. Park, Y.N. Han, et al., Degradation of ginseng saponins under mild acidic conditions, Planta Med. 44(1982) 146-149.
11. [11]
  [11] W. Xu, J.M. Wu, Z. Zhu, et al., Pentacyclic triterpenoid saponins from Silene viscidula, Helv. Chim. Acta 93(2010) 2007-2014.
12. [12]
  [12] P.Y. Liao, D. Wang, Y.J. Zhang, C.R. Yang, Dammarane-type glycosides from steamed notoginseng, J. Agric. Food Chem. 56(2008) 1751-1756.
1. [1]
  Jinyan Zhang , Fen Liu , Qian Jin , Xueyi Li , Qiong Zhan , Mu Chen , Sisi Wang , Zhenlong Wu , Wencai Ye , Lei Wang . Discovery of unusual phloroglucinol–triterpenoid adducts from Leptospermum scoparium and Xanthostemon chrysanthus by building blocks-based molecular networking. Chinese Chemical Letters, 2024, 35(6): 108881-. doi: 10.1016/j.cclet.2023.108881
2. [2]
  Chao Chen , Wang Geng , Ke Li , Qiong Lei , Zhichao Jin , Xiuhai Gan . Pyridazine: A privileged scaffold in the development of 21^st-century pesticides. Chinese Chemical Letters, 2025, 36(8): 110902-. doi: 10.1016/j.cclet.2025.110902
3. [3]
  Kang Wei , Jiayu Li , Wen Zhang , Bing Yuan , Ming-De Li , Pingwu Du . A strained π-extended [10]cycloparaphenylene carbon nanoring. Chinese Chemical Letters, 2024, 35(5): 109055-. doi: 10.1016/j.cclet.2023.109055
4. [4]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
5. [5]
  . . University Chemistry, 2024, 39(10): 0-0.
6. [6]
  Yanye Fan , Jingjing Chen , Bichun Chen , Jinyu Bai , Bowen Yang , Feng Liang , Lijing Fang . Design, synthesis and biological evaluation of Leu₁₀-teixobactin analogues. Chinese Chemical Letters, 2025, 36(4): 110075-. doi: 10.1016/j.cclet.2024.110075
7. [7]
  . . University Chemistry, 2025, 40(10): 0-0.
8. [8]
  . 第41卷第10期封面和目次. Acta Physico-Chimica Sinica, 2025, 41(10): -.
9. [9]
  Chao Chen , Wenwen Yu , Guangen Huang , Xuelian Ren , Xiangli Chen , Yixin Li , Shenggui Liang , Mengmeng Xu , Mingyue Zheng , Yaxi Yang , He Huang , Wei Tang , Bing Zhou . Asymmetric macrocyclization enabled by Rh(Ⅲ)-catalyzed CH activation: Enantioenriched macrocyclic inhibitor of Zika virus infection. Chinese Chemical Letters, 2024, 35(11): 109574-. doi: 10.1016/j.cclet.2024.109574
10. [10]
  Luyun Zhang , Ding Liu , Huri Piao , Zhenhua Jia , Fen-Er Chen . A modified Bis-OPNN phosphorus ligand for Rh-catalyzed linear-selective hydroformylation of alkenes. Chinese Chemical Letters, 2025, 36(7): 110640-. doi: 10.1016/j.cclet.2024.110640
11. [11]
  Yu Xia , Yangming Jiang , Xin-Long Ni , Qiaochun Wang , Daoping Wang . A macrocycle-based "Russian doll": The smallest cucurbit[4]uril in cucurbit[10]uril. Chinese Chemical Letters, 2024, 35(12): 109782-. doi: 10.1016/j.cclet.2024.109782
12. [12]
  Ran Cen , Yan-Yan Tang , Li-Xia Chen , Zhu Tao , Xin Xiao . A novel supramolecular assembly based on nor-seco-cucurbit[10]uril for spermine sensing and artificial light-harvesting. Chinese Chemical Letters, 2025, 36(1): 109744-. doi: 10.1016/j.cclet.2024.109744
13. [13]
  Nanjiong Pang , Yunxiang He , Mingyao Wang , Xiaoling Wang , Junling Guo , Xuepin Liao , Bi Shi . Exploiting selective isotope exchange of amino–phenolic networks for boron-10 isotopologue separation. Chinese Chemical Letters, 2025, 36(10): 110914-. doi: 10.1016/j.cclet.2025.110914
14. [14]
  Shulei Hu , Yu Zhang , Xiong Xie , Luhan Li , Kaixian Chen , Hong Liu , Jiang Wang . Rh(Ⅲ)-catalyzed late-stage C-H alkenylation and macrolactamization for the synthesis of cyclic peptides with unique Trp(C7)-alkene crosslinks. Chinese Chemical Letters, 2024, 35(8): 109408-. doi: 10.1016/j.cclet.2023.109408
15. [15]
  Ying Zhao , Yin-Hang Chai , Tian Chen , Jie Zheng , Ting-Ting Li , Francisco Aznarez , Li-Long Dang , Lu-Fang Ma . Size-controlled synthesis and near-infrared photothermal response of Cp* Rh-based metalla[2]catenanes and rectangular metallamacrocycles. Chinese Chemical Letters, 2024, 35(6): 109298-. doi: 10.1016/j.cclet.2023.109298
16. [16]
  Xinghui Yao , Zhouyu Wang , Da-Gang Yu . Sustainable electrosynthesis: Enantioselective electrochemical Rh(III)/chiral carboxylic acid-catalyzed oxidative CH cyclization coupled with hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(9): 109916-. doi: 10.1016/j.cclet.2024.109916
17. [17]
  Jianing He , Xiao Wang , Zijian Wang , Ruize Jiang , Ke Wang , Rui Zhang , Huilin Wang , Baokang Geng , Hongyi Gao , Shuyan Song , Hongjie Zhang . Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis. Chinese Chemical Letters, 2025, 36(2): 109640-. doi: 10.1016/j.cclet.2024.109640
18. [18]
  Yupeng TANG , Haiying YANG , Fan JIN , Nan LI . Hydrogen storage properties of C₆S₆Li₆: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1827-1839. doi: 10.11862/CJIC.20240460
19. [19]
  Xue-Wen Wu , Bin-Bao Wang , Yu Qin , Yong-Xiang Huang , Muhammad Aurang Zeb , Bin Cheng , Xiao-Li Li , Chang-Bo Zheng , Wei-Lie Xiao . Diterpenoids with unexpected 5/6/6-fused ring system and its dimer from Strophioblachia glandulosa. Chinese Chemical Letters, 2025, 36(8): 110584-. doi: 10.1016/j.cclet.2024.110584
20. [20]
  Jindong Hao , Yufen Lv , Shuyue Tian , Chao Ma , Wenxiu Cui , Huilan Yue , Wei Wei , Dong Yi . Additive-free synthesis of β-keto phosphorodithioates via geminal hydro-phosphorodithiolation of sulfoxonium ylides with P₄S₁₀ and alcohols. Chinese Chemical Letters, 2024, 35(9): 109513-. doi: 10.1016/j.cclet.2024.109513

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1116)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142