Citation: Na Li, Rui Chen, Jing Miao, Peng Zhou, Hai-Bin Yu, Tie-Hong Chen. Synthesis of single crystal-like hierarchically mesoporous titanosilicate Ti-SBA-1[J]. Chinese Chemical Letters, ;2015, 26(10): 1269-1272. doi: 10.1016/j.cclet.2015.05.053 shu

Synthesis of single crystal-like hierarchically mesoporous titanosilicate Ti-SBA-1

Na Li ^1,3 ,
Rui Chen ¹ ,
Jing Miao ² ,
Peng Zhou ² ,
Hai-Bin Yu ² ,
Tie-Hong Chen ^1,,

1.
1 Institute of New Catalytic Materials Science, Key Laboratory of Advanced Energy Materials Chemistry(MOE), College of Chemistry, School of Materials Science and Engineering, Nankai University, Tianjin 300071, China;
2.
2 CNOOC Tianjin Chemical Research & Design Institute, Tianjin 300131, China;
3.
3 College of Metallurgy Engineering, Hunan University of Technology, Zhuzhou 412007, China

Corresponding author: Tie-Hong Chen,
Received Date: 16 April 2015
Available Online: 22 May 2015
Fund Project: RFDP (No. 20120031110005) (No. 13JCYBJC18300) the Technology Planning Project of Hunan Province (No. 2014SK2019) (No. 20120031110005) National Science Foundation for Post-doctoral Scientists of China (No. 2014T70774) (No. 2014SK2019)the Scientific Research Fund of Hunan Provincial Education Department (No. 14C0343). (No. 2014T70774)

Hierarchically mesoporous titanosilicate Ti-SBA-1 was synthesized with organic mesomorphous complexes of polyelectrolyte (poly(acrylic acid) (PAA)) and cationic surfactant (hexadecyl pyridinium chloride (CPC)) as template, tetraethylsiloxane as silica source and titanium ethoxide as titanium source. By adjusting the amount of titanium ethoxide in the synthesis, a series of Ti-SBA-1 particles with different Si/Ti ratio (79-180) were prepared. After incorporation of Ti into the silica framework thewellordered cubic Pm3n mesostructure remained, as well as the morphology, particle size. UV-vis DR spectra of the Ti-SBA-1 materials indicated that incorporated titaniumspecies existed in a highly dispersed state and exhibited tetrahedral and octahedral coordination in the silica framework.
- Ti-SBA-1,
- Hierarchical,
- Mesoporous,
- Titanosilicate
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