Citation:
Yao Chen, Xin-Wei Dou, Meng-Meng Zhang, Xuan Lu, Yu-Jun Qin, Pu Zhang, Zhi-Xin Guo. The fabrication of flower-like graphene/octadecylamine composites[J]. Chinese Chemical Letters,
;2015, 26(9): 1144-1146.
doi:
10.1016/j.cclet.2015.05.045
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Three-dimensional flower-like nanomaterials have wide application due to the large specific surface area. In this letter, the morphology of octadecylamine (ODA) from several common solvents is studied and it is found that from the chloroform and acetone solution, ODA assembles into petal-like structure, which further forms the spherical or flower-like architecture. Furthermore, the composite materials incorporated reduced graphene oxide (rGO) and ODA could well keep the flower-shaped structure of ODA. XRD results show that the introduction of graphene has little influence on the structure of ODA and contact angle test indicates good hydrophobic performance of the rGO/ODA material.
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Keywords:
- Graphene,
- Octadecylamine,
- Flower-like,
- Composite
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[1]
[1] W.L. Noorduin, A. Grinthal, L. Mahadevan, J. Aizenberg, Rationally designed complex, hierarchical microarchitectures, Science 340(2013) 832-837.
-
[2]
[2] C.J. Martinez, B. Hockey, C.B. Montgomery, S. Semancik, Porous tin oxide nanostructured microspheres for sensor applications, Langmuir 21(2005) 7937-7944.
-
[3]
[3] Z.H. Bao, M.R. Weatherspoon, S. Shian, et al., Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas, Nature 446(2007) 172-175.
-
[4]
[4] Z.Y. Wang, L. Zhou, X.W. Lou, Metal oxide hollow nanostructures for lithium-ion batteries, Adv. Mater. 24(2012) 1903-1911.
-
[5]
[5] D. Peer, J.M. Karp, S. Hong, et al., Nanocarriers as an emerging platform for cancer therapy, Nat. Nanotechnol. 2(2007) 751-760.
-
[6]
[6] T. Nakanishi, K. Ariga, T. Michinobu, et al., Flower-shaped supramolecular assemblies:hierarchical organization of a fullerene bearing long aliphatic chains, Small 3(2007) 2019-2023.
-
[7]
[7] X. Zhang, M. Takeuchi, Controlled fabrication of fullerene C60 into microspheres of nanoplates through porphyrin-polymer-assisted self-assembly, Angew. Chem. Int. Ed. 48(2009) 9646-9651.
-
[8]
[8] B.I. Kharisov, A review for synthesis of nanoflowers, Recent Pat. Nanotechnol. 2(2008) 190-200.
-
[9]
[9] Y.H. Sun, P.P. Dong, X. Lang, J.M. Nan, A novel rose flower-like SnO hierarchical structure synthesized by a hydrothermal method in an ethanol/water system, Chin. Chem. Lett. 25(2014) 915-918.
-
[10]
[10] Y. Wang, Z.M. Liu, B.X. Han, et al., Fabrication of flowerlike polymer superstructures using polymer/zeolite composites prepared with supercritical CO2, J. Phys. Chem. B 109(2005) 2605-2609.
-
[11]
[11] C.Q. Zhou, J. Han, R. Guo, Controllable synthesis of polyaniline multidimensional architectures:from plate-like structures to flower-like superstructures, Macromolecules 41(2008) 6473-6479.
-
[12]
[12] H. Zhao, X.R. Guo, S.L. He, et al., Complex self-assembly of pyrimido[4,5-d]pyrimidine nucleoside supramolecular structures, Nat. Commun. 5(2014) 3108.
-
[13]
[13] K. Zhang, A. Geissler, X.L. Chen, et al., Polymeric flower-like microparticles from self-assembled cellulose stearoyl esters, ACS Macro Lett. 4(2015) 214-219.
-
[14]
[14] J. Ge, J.D. Lei, R.N. Zare, Protein-inorganic hybrid nanoflowers, Nat. Nanotechnol. 7(2012) 428-432.
-
[15]
[15] Y.L. Lee, Surface characterization of octadecylamine films prepared by Langmuir-Blodgett and vacuum deposition methods by dynamic contact angle measurements, Langmuir 15(1999) 1796-1801.
-
[16]
[16] Y.F. Xu, D.K. Ma, X.A. Chen, D.P. Yang, S.M. Huang, Bisurfactant-controlled synthesis of three-dimensional YBO3/Eu3+ architectures with tunable wettability, Langmuir 25(2009) 7103-7108.
-
[17]
[17] J.J. Benitez, M.A. San-Miguel, S. Dominguez-Meister, J.A. Heredia-Guerrero, M. Salmeron, Structure and chemical state of octadecylamine self-assembled monolayers on mica, J. Phys. Chem. C 115(2011) 19716-19723.
-
[18]
[18] J.L. Zou, F. Kim, Diffusion driven layer-by-layer assembly of graphene oxide nanosheets into porous three-dimensional macrostructures, Nat. Commun. 5(2014) 5254.
-
[19]
[19] Z.Y. Lin, Y. Liu, C.P. Wong, Facile fabrication of superhydrophobic octadecylaminefunctionalized graphite oxide film, Langmuir 26(2010) 16110-16114.
-
[20]
[20] S. Choudhary, H.P. Mungse, O.P. Khatri, Dispersion of alkylated graphene in organic solvents and its potential for lubrication applications, J. Mater. Chem. 22(2012) 21032-21039.
-
[21]
[21] Z.L. Chen, F.Y. Kam, V. Keerthi, et al., Efficient surfactant-free and chemical reductant-free solvothermal deoxidation of solution-processable sub-stoichiometric graphene oxide, J. Mater. Chem. C 1(2013) 7246-7254.
-
[22]
[22] J.H. Xu, M. Li, Y. Zhao, Q.H. Lu, Advance of wetting behavior research on the superhydrophobic surface with micro- and nano-structures, Prog. Chem. 18(2006) 1425-1433.
-
[23]
[23] K.G. Patil, V. Santhanam, S.K. Biswas, K.G. Ayappa, Combined atomic force microscopy and modeling study of the evolution of octadecylamine films on a mica surface, J. Phys. Chem. C 114(2010) 3549-3559.
-
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