Citation: Ya-Li Shi, Yuan-Yuan Pan, Li-Na Liang, Ya-Qi Cai. An on-line solid phase extraction-liquid chromatography tandem mass spectrometry method for the determination of perfluoroalkyl substances in the Antarctic ice core samples[J]. Chinese Chemical Letters, ;2015, 26(9): 1073-1078. doi: 10.1016/j.cclet.2015.05.038 shu

An on-line solid phase extraction-liquid chromatography tandem mass spectrometry method for the determination of perfluoroalkyl substances in the Antarctic ice core samples

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1 State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China;
2.
2 Thermo Fisher Scientific(China)Co., Ltd., Beijing 100080, China

Corresponding author: Ya-Qi Cai,
Received Date: 20 January 2015
Available Online: 19 May 2015
Fund Project: This work was jointly supported by the National Natural Science Foundation of China (Nos. 21377145, 21321004) (Nos. 21377145, 21321004)the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB01020300). (No. XDB01020300)

An on-line solid phase extraction-high performance liquid chromatography-tandemmass spectrometry method for the analysis of perfluoroalkyl substances (PFASs) in water samples was developed. The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column, sample loading rate and loading volume, and the concentration of ammonium acetate in mobile phase. Under the optimal condition, the analytical method displayed good linearity (r² > 0.99) for 12 PFASs (C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids) over a concentration range of 0.5-100 ng/L. The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations (RSD) of five consecutive analyses were less than 10% for 1 ng/L standard solution. Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples. The recoveries of all perfluoroalkyl substances were in a range of 73%-117% when the sampleswere spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L.
- Perfluoroalkyl substances,
- On-line solid phase extraction,
- LC-MS/MS,
- Antarctic ice cores
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