Citation: Ya-Li Shi, Yuan-Yuan Pan, Li-Na Liang, Ya-Qi Cai. An on-line solid phase extraction-liquid chromatography tandem mass spectrometry method for the determination of perfluoroalkyl substances in the Antarctic ice core samples[J]. Chinese Chemical Letters, ;2015, 26(9): 1073-1078. doi: 10.1016/j.cclet.2015.05.038 shu

An on-line solid phase extraction-liquid chromatography tandem mass spectrometry method for the determination of perfluoroalkyl substances in the Antarctic ice core samples

1.
1 State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China;
2.
2 Thermo Fisher Scientific(China)Co., Ltd., Beijing 100080, China

Corresponding author: Ya-Qi Cai,
Received Date: 20 January 2015
Available Online: 19 May 2015
Fund Project: This work was jointly supported by the National Natural Science Foundation of China (Nos. 21377145, 21321004) (Nos. 21377145, 21321004)the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB01020300). (No. XDB01020300)

An on-line solid phase extraction-high performance liquid chromatography-tandemmass spectrometry method for the analysis of perfluoroalkyl substances (PFASs) in water samples was developed. The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column, sample loading rate and loading volume, and the concentration of ammonium acetate in mobile phase. Under the optimal condition, the analytical method displayed good linearity (r² > 0.99) for 12 PFASs (C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids) over a concentration range of 0.5-100 ng/L. The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations (RSD) of five consecutive analyses were less than 10% for 1 ng/L standard solution. Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples. The recoveries of all perfluoroalkyl substances were in a range of 73%-117% when the sampleswere spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L.
- Perfluoroalkyl substances,
- On-line solid phase extraction,
- LC-MS/MS,
- Antarctic ice cores
1. [1]
  [1] S. Posner, Perfluorinated compounds:occurrence and uses in products, in:T.P. Knepper, F.T. Lange (Eds.), Polyfluorinated Chemicals and Transformation Products, Springer, Berlin Heidelberg, 2012, pp. 25-39.
2. [2]
  [2] R.C. Buck, J. Franklin, U. Berger, et al., Perfluoroalkyl and polyfluoroalkyl substances in the environment:terminology, classification and origins, Integr. Environ. Assess. Manag. 7(2011) 513-541.
3. [3]
  [3] J.S. Wang, Y.T. Zhang, W. Zhang, et al., Association of perfluorooctanoic acid with HDL cholesterol and circulating miR-26b and miR-199-3p in workers of a fluorochemical plant and nearby residents, Environ. Sci. Technol. 46(2012) 9274-9281.
4. [4]
  [4] M.J. Lopez-Espinosa, T. Fletcher, B. Armstrong, et al., Association of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) with age of puberty among children living near a chemical plant, Environ. Sci. Technol. 45(2011) 8160-8166.
5. [5]
  [5] B.B. Gump, Q. Wu, A.K. Dumas, K. Kannan, Perfluorochemical (PFC) exposure in children:associations with impaired response inhibition, Environ. Sci. Technol. 45(2011) 8151-8159.
6. [6]
  [6] U. S. Environmental Protection Agency (US EPA), New Chemical Review of Alternatives for PFOA and Related Chemicals, 2012 http://www.epa.gov/oppt/pfoa/pubs/altnewchems.html.
7. [7]
  [7] ENV/JM/RD (2002) 17/FINAL, Hazard assessment of perfluorooctane sulfonate (PFOS) and its salts. http://www.oecd.org/chemicalsafety/risk-assessment/2382880.pdf.
8. [8]
  [8] United Nations Environment Programme, Governments Unite to Step-up Reduction on Global DDT Reliance and Add Nine New Chemicals Under International Treaty, UNEP, 2009 http://chm.pops.int/Convention/Press release COP4 Geneva 8 May 2009/tabid/542/language/en-US/Default.aspx.
9. [9]
  [9] Y.N. Liu, A.S. Pereira, S. Beesoon, et al., Temporal trends of perfluorooctanesulfonate isomer and enantiomer patterns in archived Swedish and American serum samples, Environ. Int. 75(2015) 215-222.
10. [10]
  [10] Z. Zhou, Y.L. Shi, R. Vestergren, et al., Highly elevated serum concentrations of perfluoroalkyl substances in fishery employees from Tangxun Lake, China, Environ. Sci. Technol. 48(2014) 3864-3874.
11. [11]
  [11] J.W. Teng, S.Z. Tang, S.Y. Qu, Determination of perfluorooctanesulfonate and perfluorooctanoate in water samples by SPE-HPLC/electrospray ion trap mass spectrometry, Microchem. J. 93(2009) 55-59.
12. [12]
  [12] J.M. Keller, A.M. Calafat, K. Kato, et al., Determination of perfluorinated alkyl acid concentrations in human serum and milk standard reference materials, Anal. Bioanal. Chem. 397(2010) 439-451.
13. [13]
  [13] A. Navarrete, M.P. Martínez-Alcázar, I. Durá n, et al., Simultaneous online SPE-HPLC-MS/MS analysis of docetaxel, temsirolimus and sirolimus in whole blood and human plasma, J. Chromatogr. B:Analyt. Technol. Biomed. Life Sci. 921/922(2013) 35-42.
14. [14]
  [14] F. Guo, Q. Liu, G.B. Qu, et al., Simultaneous determination of five estrogens and four androgens in water samples by online solid-phase extraction coupled with high-performance liquid chromatography-tandem mass spectrometry, J. Chromatogr. A 1281(2013) 9-18.
15. [15]
  [15] F. Gosetti, U. Chiuminatto, D. Zampieri, et al., Determination of perfluorochemicals in biological, environmental and food samples by an automated online solid phase extraction ultra high performance liquid chromatography tandem mass spectrometry method, J. Chromatogr. A 1217(2010) 7864-7872.
16. [16]
  [16] P. Zhang, Y.L. Shi, Y.Q. Cai, S.F. Mou, Determination of perfluorinated compounds in water samples by high performance liquid chromatography-electrospray tandem mass spectrometry, Chin. J. Anal. Chem. 35(2007) 969-972.
17. [17]
  [17] S. Jiang, Y.S. Li, B. Sun, Determination of trace level of perchlorate in Antarctic snow and ice by ion chromatography coupled with tandem mass spectrometry using an automated sample on-line preconcentration method, Chin. Chem. Lett. 24(2013) 311-314.
1. [1]
  Guo-Ping Yin , Ya-Juan Li , Li Zhang , Ling-Gao Zeng , Xue-Mei Liu , Chang-Hua Hu . Citrinsorbicillin A, a novel homotrimeric sorbicillinoid isolated by LC-MS-guided with cytotoxic activity from the fungus Trichoderma citrinoviride HT-9. Chinese Chemical Letters, 2024, 35(8): 109035-. doi: 10.1016/j.cclet.2023.109035
2. [2]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
3. [3]
  Lu Huang , Jiang Wang , Hong Jiang , Lanfang Chen , Huanwen Chen . On-line determination of selenium compounds in tea infusion by extractive electrospray ionization mass spectrometry combined with a heating reaction device. Chinese Chemical Letters, 2025, 36(1): 109896-. doi: 10.1016/j.cclet.2024.109896
4. [4]
  Xinyue Han , Yunhan Yang , Jiayin Lu , Yuxiang Lin , Dongxue Zhang , Ling Lin , Liang Qiao . Efficient serum lipids profiling by TiO₂-dopamin-assisted MALDI-TOF MS for breast cancer detection. Chinese Chemical Letters, 2025, 36(5): 110183-. doi: 10.1016/j.cclet.2024.110183
5. [5]
  Jinqi Yang , Xiaoxiang Hu , Yuanyuan Zhang , Lingyu Zhao , Chunlin Yue , Yuan Cao , Yangyang Zhang , Zhenwen Zhao . Direct observation of natural products bound to protein based on UHPLC-ESI-MS combined with molecular dynamics simulation. Chinese Chemical Letters, 2025, 36(5): 110128-. doi: 10.1016/j.cclet.2024.110128
6. [6]
  Pengyu Chen , Beibei Chen , Man He , Yuxi Zhou , Lei Lei , Jian Han , Bingsheng Zhou , Ligang Hu , Bin Hu . Nanoplastics and nano-ZnO facilitate Cd accumulation in zebrafish larvae via a distinct pathway: Revelation by LA-ICP-MS imaging. Chinese Chemical Letters, 2025, 36(2): 109908-. doi: 10.1016/j.cclet.2024.109908
7. [7]
  Dan Zhou , Liangjin Bao , Haoqi Long , Duo Zhou , Yuwei Xu , Bo Wang , Chuanqin Xia , Liang Xian , Chengbin Zheng . Capillary electrophoresis as sample introduction system for highly sensitive and interference-free determination of ⁹⁹Tc by ICP-MS. Chinese Chemical Letters, 2025, 36(4): 110093-. doi: 10.1016/j.cclet.2024.110093
8. [8]
  Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135
9. [9]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
10. [10]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
11. [11]
  Yong-Fang Shi , Sheng-Hua Zhou , Zuju Ma , Xin-Tao Wu , Hua Lin , Qi-Long Zhu . From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation. Chinese Journal of Structural Chemistry, 2025, 44(1): 100455-100455. doi: 10.1016/j.cjsc.2024.100455
12. [12]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
13. [13]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
14. [14]
  Pengcheng Su , Shizheng Chen , Zhihong Yang , Ningning Zhong , Chenzi Jiang , Wanbin Li . Vapor-phase postsynthetic amination of hypercrosslinked polymers for efficient iodine capture. Chinese Chemical Letters, 2024, 35(9): 109357-. doi: 10.1016/j.cclet.2023.109357
15. [15]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
16. [16]
  Mengjia Luo , Yi Qiu , Zhengyang Zhou . Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446-100446. doi: 10.1016/j.cjsc.2024.100446
17. [17]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
18. [18]
  Kezhen Qi , Shu-yuan Liu , Ruchun Li . Selective dissolution for stabilizing solid electrolyte interphase. Chinese Chemical Letters, 2024, 35(5): 109460-. doi: 10.1016/j.cclet.2023.109460
19. [19]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
20. [20]
  Jing Guo . Stacking solid-state electrolyte and aluminum pellets for anode-free solid-state batteries. Chinese Chemical Letters, 2025, 36(5): 110764-. doi: 10.1016/j.cclet.2024.110764

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(796)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142