Citation: Cai-Li Sun, Jiang-Fei Xu, Yu-Zhe Chen, Li-Ya Niu, Li-Zhu Wua, Chen-Ho Tung, Qing-Zheng Yang. Monofunctionalized pillar[5]arene-based stable [1]pseudorotaxane[J]. Chinese Chemical Letters, ;2015, 26(7): 843-846. doi: 10.1016/j.cclet.2015.05.030 shu

Monofunctionalized pillar[5]arene-based stable [1]pseudorotaxane

Cai-Li Sun ^a,b,c ,
Jiang-Fei Xu ^a ,
Yu-Zhe Chen ^a,, ,
Li-Ya Niu ^a ,
Li-Zhu Wua ^a ,
Chen-Ho Tung ^a ,
Qing-Zheng Yang ^a,b,,

1.
a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
2.
b College of Chemistry, Beijing Normal University, Beijing 100875, China;
3.
c University of the Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Yu-Zhe Chen, Qing-Zheng Yang,
Received Date: 27 March 2015
Available Online: 22 April 2015
Fund Project: We are grateful for the financial support from the 973 Program (No. 2013CB933800) (No. 2013CB933800) the National Natural Science Foundation of China (Nos. 21222210, 21474124, 21472202). (Nos. 21222210, 21474124, 21472202)

We reported a new monofunctionalized pillar[5]arene bearing imidazolium moiety that formed stable [1]pseudorotaxane even at high concentration (100 mmol/L) in chloroform. The self-assembly was detailed investigated by multiple methods, including varying concentration ¹H NMR, 2D COSY NMR, 2D NOESY NMR, viscosity measurements, 2D DOSY NMR, and HR-ESI-MS analysis. [1]Rotaxane was obtained efficiently through photo thiol-ene reaction which further confirmed the formation of [1]pseudorotaxane.
- Pillar[5]arene,
- Self-assembly,
- [1]pseudorotaxanes,
- Thiol-ene reaction
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