Citation: Shu-Ming Zhang, Gui-Xiang Wang, Peng Guo, Yu-Huan Chen. Zinc(II) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid: Synthesis, structures and luminescent properties[J]. Chinese Chemical Letters, ;2015, 26(9): 1079-1084. doi: 10.1016/j.cclet.2015.05.025 shu

Zinc(II) coordination architectures based on 5-(1H-tetrazol-1-yl)-isophthalic acid: Synthesis, structures and luminescent properties

1.
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

Corresponding author: Shu-Ming Zhang,
Received Date: 25 February 2015
Available Online: 11 May 2015
Fund Project: This work is supported by the Natural Science Foundation of Hebei Province (No. B2012202019) (No. B2012202019)the National Natural Science Foundation of China (No. 21206027). (No. 21206027)

With different pyridine-analogs as auxiliary ligands, three novel Zn(II) complexes (1-3) based on 5-(1H-tetrazol-1-yl) isophthalic acid (H₂L) have been synthesized and structurally characterized. Single crystal X-ray diffraction analyses of complexes 1-3 show the presence of tetrazolyl group, as well as the coordination behavior of the auxiliary ligands as critical factors determining the structures of such Zn(II)-carboxylate coordination architectures. In addition, the resulting complexes all exhibit luminescence properties in the solid state at room temperature.
- Zn(II)-carboxylate complex,
- Pyridine-analogs,
- Structure-tuning,
- Luminescent properties
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