Citation: Maryam Mirabedini, Elaheh Motamedi, Mohammad Zaman Kassaee. Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A³-coupling synthesis of propargylamines[J]. Chinese Chemical Letters, ;2015, 26(9): 1085-1090. doi: 10.1016/j.cclet.2015.05.021 shu

Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A³-coupling synthesis of propargylamines

1.
1 Department of Chemistry, Tarbiat Modares University, P. O. Box 14155-175, Tehran, Iran;
2.
2 Department of Food Nanotechnology, Research Institute of Food Science and Technology(RIFST), Mashhad 91735-147, Iran

Corresponding author: Mohammad Zaman Kassaee,
Received Date: 8 February 2015
Available Online: 29 April 2015

Magnetically separable CuO nanoparticles supported on graphene oxide (Fe₃O₄ NPs/GO-CuO NPs) is synthesized and characterized for the preparation of propargylamines in EtOH, at 90℃. Fe₃O₄ NPs/GO-CuO NPs is found to be an efficient catalyst for the A³-coupling of aldehydes, amines, and alkynes through C-H activation. Both aromatic and aliphatic aldehydes and alkynes are combined with secondary amines to provide a wide range of propargylamines in moderate to excellent yields.
- CuO,
- Graphene oxide,
- Fe₃O₄,
- A³-coupling,
- Nano-catalyst,
- Magnetic nanoparticles
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A3-coupling synthesis of propargylamines

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通讯作者: 陈斌, bchen63@163.com

Magnetic CuO nanoparticles supported on graphene oxide as an efficient catalyst for A³-coupling synthesis of propargylamines