Citation: Hai-Xia Wang, Zhen-Ning Yan, Xiang-Li Wen, Yun-Xia Kang, Shuang-Yan Zhang. A bismuth(III) PVC membrane ion selective electrode based on 5-(3,4,5-trimethoxyphenyl)-4-amino-1,2,4-triazole-3-thiol[J]. Chinese Chemical Letters, ;2015, 26(9): 1147-1149. doi: 10.1016/j.cclet.2015.04.036 shu

A bismuth(III) PVC membrane ion selective electrode based on 5-(3,4,5-trimethoxyphenyl)-4-amino-1,2,4-triazole-3-thiol

1.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Zhen-Ning Yan,
Received Date: 23 January 2015
Available Online: 23 April 2015
Fund Project: This work was supported by the Science Foundation of Henan Province (No. 142102310336). (No. 142102310336)

The construction, performance characteristics and application of a new bismuth(III) PVC membrane electrode based on 5-(3,4,5-trimethoxyphenyl)-4-amino-1,2,4-triazole-3-thiol are reported in this paper. The designed sensor exhibited a Nernstian response for Bi³⁺ ion ranging from 5.0×10^-7 mol/L to 1.0×10^-2 mol/L with a slope of 19.8 mV/decade. The operational pH range of the sensor is 3.0-6.0. The electrode shows a response time of 6 s and can be used for at least five weeks without any considerable divergence in potentials. It exhibits very good selectivity relative to a wide variety of alkali, alkaline earth, transition and heavy metal ions. The proposed electrode could be used as an indicator electrode in potentiometric titration of Bi³⁺ ions with EDTA and in the determination of Bi³⁺ content in stomach medicine.
- Bi³⁺,
- PVC-membrane,
- Ion-selective electrode,
- Potentiometry,
- Ionophore
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