Citation: Hai-Xia Wang, Zhen-Ning Yan, Xiang-Li Wen, Yun-Xia Kang, Shuang-Yan Zhang. A bismuth(III) PVC membrane ion selective electrode based on 5-(3,4,5-trimethoxyphenyl)-4-amino-1,2,4-triazole-3-thiol[J]. Chinese Chemical Letters, ;2015, 26(9): 1147-1149. doi: 10.1016/j.cclet.2015.04.036 shu

A bismuth(III) PVC membrane ion selective electrode based on 5-(3,4,5-trimethoxyphenyl)-4-amino-1,2,4-triazole-3-thiol

1.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Zhen-Ning Yan,
Received Date: 23 January 2015
Available Online: 23 April 2015
Fund Project: This work was supported by the Science Foundation of Henan Province (No. 142102310336). (No. 142102310336)

The construction, performance characteristics and application of a new bismuth(III) PVC membrane electrode based on 5-(3,4,5-trimethoxyphenyl)-4-amino-1,2,4-triazole-3-thiol are reported in this paper. The designed sensor exhibited a Nernstian response for Bi³⁺ ion ranging from 5.0×10^-7 mol/L to 1.0×10^-2 mol/L with a slope of 19.8 mV/decade. The operational pH range of the sensor is 3.0-6.0. The electrode shows a response time of 6 s and can be used for at least five weeks without any considerable divergence in potentials. It exhibits very good selectivity relative to a wide variety of alkali, alkaline earth, transition and heavy metal ions. The proposed electrode could be used as an indicator electrode in potentiometric titration of Bi³⁺ ions with EDTA and in the determination of Bi³⁺ content in stomach medicine.
- Bi³⁺,
- PVC-membrane,
- Ion-selective electrode,
- Potentiometry,
- Ionophore
1. [1]
  [1] Z. Xing, J. Wang, S.C. Zhang, X.R. Zhang, Determination of bismuth in solid samples by hydride generation atomic fluorescence spectrometry with a dielectric barrier discharge atomizer, Talanta 80(2009) 139-142.
2. [2]
  [2] S. Moyano, R.G. Wuilloud, R.A. Olsina, J.A. Gá squez, L.D. Martinez, On-line preconcentration system for bismuth determination in urine by flow injection hydride generation inductively coupled plasma atomic emission spectrometry, Talanta 54(2001) 211-219.
3. [3]
  [3] S. Itoh, S. Kaneco, K. Ohta, T. Mizuno, Determination of bismuth in environmental samples with Mg-W cell-electrothermal atomic absorption spectrometry, Anal. Chim. Acta 379(1999) 169-173.
4. [4]
  [4] R. Ohzeki, T. Kambara, Properties of a membrane electrode based on liquid ion exchanger incorporated in poly(vinyl chloride) and its application to potentiometric titration of bismuth(III), J. Electroanal. Chem. Interface Electrochem. 88(1978) 85-90.
5. [5]
  [5] R.K. Mahajan, R.K. Puri, G. Bhargava, M.P. Mahajan, 1,3,4-Trisubstituted-2-azetidinone derivatives as novel receptors for bismuth (III) ion-selective electrodes:application in pharmaceutical and glass samples, Anal. Lett. 42(2009) 2444-2459.
6. [6]
  [6] S.V. Kharitonov, Polymeric membrane ion-selective electrode for determination of bismuth (III) in pharmaceutical substances, J. Pharm. Biomed. Anal. 30(2002) 181-187.
7. [7]
  [7] Z.N. Yan, S.Q. Wang, H.X. Wang, S.Y. Wu, Bismuth (III) PVC membrane ion selective electrodes based on two compounds:acylhydrazone and thiosemicarbazone with 1,3,4-thiadiazole, Mater. Sci. Eng. C 33(2013) 2562-2568.
8. [8]
  [8] L. Liu, L. Wang, H.Z. Yin, Y.J. Li, X.W. He, The preparation and application of bismuth (III) ion-selective electrode based on nanoparticles of bismuth sulfide, Anal. Lett. 39(2006) 879-890.
9. [9]
  [9] D.M.S. Paqhaleh, L. Hashemi, V. Amani, A. Morsali, A.A. Aminjanov, Synthesis of two new nano-structured mercury (II) complexes with 4-methyl-4H-1,2,4-triazole-3-thiol ligand by sonochemical method, Inorg. Chim. Acta 407(2013) 1-6.
10. [10]
  [10] R.F. Zhang, Q.F. Wang, Q.L. Li, C.L. Ma, Syntheses and characterization of triorganotin (IV) complexes of Schiff base derive from 4-amino-5-phenyl-4H-1,2,4-triazole-3-thiol and 5-amino-1,3,4-thiadiazole-2-thiol with p-phthalaldehyde, Inorg. Chim. Acta 362(2009) 2762-2769.
11. [11]
  [11] T. George, T.D. Mehta, R. Tahilramani, J. David, P.K. Talwalker, Synthesis of some striazoles with potential analgesic and antiinflammatory activities, J. Med. Chem. 14(1971) 335-338.
12. [12]
  [12] H.T. Du, H.J. Du, Synthesis and biological activity of 6-(substituted)-3-(3,4,5-trimethoxyphenyl)-1,2,4-triazolo[3,4-b] [1,3,4] thiadiazole, Chin. J. Org. Chem. 30(2010) 137-141.
13. [13]
  [13] M.B. Gholivand, Y. Mozaffari, PVC-based bis (2-nitrophenyl) disulfide sensor for zinc ions, Talanta 59(2003) 399-407.
14. [14]
  [14] W. Zhang, L. Jenny, U.E. Spichiger, A comparison of neutral Mg²⁺-selective ionophores in solvent polymeric membranes:complex stoichiometry and lipophilicity, Anal. Sci. 16(2000) 11-18.
15. [15]
  [15] E. Bakker, Selectivity of liquid membrane ion-selective electrodes, Electroanalysis 9(1997) 7-12.
16. [16]
  [16] Y. Umezawa, P. Buhlmann, K. Umezawa, K. Tohda, S. Amemiya, Potentiometric selectivity coefficients of ion-selective electrodes. Part I. Inorganic cations (Technical Report), Pure Appl. Chem. 72(2000) 1851-2082.
17. [17]
  [17] Y. Umezawa, K. Umezawa, H. Sato, Selectivity coefficients for ion-selective electrodes:recommended methods for reporting K_A,B^pot values (IUPAC technical report), Pure Appl. Chem. 67(1995) 507-518.
18. [18]
  [18] M.F. de Souza Teixeira, A.Z. Pinto, O. Fatibello-Filho, Ion-selective electrode for bismuth (III) in ethylenediamintetraacetate medium, Talanta 45(1997) 249-255.
19. [19]
  [19] D. Li, T. Sun, The development and application of the bismuth ion-modified carbon paste electrode, Phys. Testing Chem. Anal. Part B:Chem. Anal. 42(2006) 359-360.
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沈阳化工大学材料科学与工程学院沈阳 110142