Citation: Ji-Feng Wang, Bing-Bing Shi, Gang Li. Preparations and characterizations of two MOFs constructed with hydroxylphenyl imidazole dicarboxylate[J]. Chinese Chemical Letters, ;2015, 26(9): 1059-1064. doi: 10.1016/j.cclet.2015.04.022 shu

Preparations and characterizations of two MOFs constructed with hydroxylphenyl imidazole dicarboxylate

1.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Gang Li,
Received Date: 22 January 2015
Available Online: 1 April 2015
Fund Project: We gratefully acknowledge the financial support by the National Natural Science Foundation of China (No. 21341002) (No. 21341002)

Using the hydrothermal reactions of Mn(II) and Ba(II) salts with 2-(3-hydroxylphenyl)-1H-imidazole-4,5-dicarboxylic acid (m-OHPhH₃IDC), two novel metal-organic frameworks, namely, {[Mn(m-OHPhHIDC)(H₂O)]·2H₂O}_n (1) and {[Ba(m-OHPhH₂IDC)₂(H₂O)₃] ·2H₂O}_n (2) have been synthesized and structurally characterized by single-crystal X-ray crystallography, elemental analyses, and IR spectroscopy. Complex 1 features a novel non-interpenetrated three-dimensional (3,4)-connected network with one-dimensional open channels. Complex 2 exhibits a two-dimensional layered structure with rhombic grids. The role of the central metals in the formation of final architectures has been discussed. Furthermore, luminescent and thermal properties of the two complexes have been studied.
- Imidazole dicarboxylate,
- Metal-organic frameworks,
- Manganese,
- Barium,
- Property
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