Citation: Shu-Yun Zhu, Hong-Yu Guo, Fa-Fu Yang, Zu-Sheng Wang. Thiacalix[4]arene 1,2,3-triazole-polyethylene glycol polymers: Synthesis and dye adsorption properties[J]. Chinese Chemical Letters, ;2015, 26(9): 1091-1095. doi: 10.1016/j.cclet.2015.03.031 shu

Thiacalix[4]arene 1,2,3-triazole-polyethylene glycol polymers: Synthesis and dye adsorption properties

1.
1 College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
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2 Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China

Corresponding author: Fa-Fu Yang,
Received Date: 13 January 2015
Available Online: 17 March 2015
Fund Project: Financial support from the National Natural Science Foundation of China (No: 21406036) (No: 21406036) Fujian Natural Science Foundation of China (No. 2014J01034) (No. 2014J01034) Project of Fujian provincial department of education (Nos. JA11044, JA10056, JB13011) (Nos. JA11044, JA10056, JB13011)

By reacting alkynylthiacalix[4]arenes with polyethylene glycol azido compounds, a series of novel thiacalix[4]arene 1,2,3-triazole-polyethylene glycol netty polymerswere conveniently prepared in good yields. Their structures and morphologies were studied by ¹H NMR, IR, and elemental analysis and SEM images. On average, approximately 28-31 thiacalixarene units exist in each polymeric molecule. These novel polymers possess excellent adsorption ability for both cationic and anionic dyes. The saturation adsorption capacity for Congo red reached 1.3-1.4 mmol/g. They exhibit high and stable adsorption ability in the scope of pH 5-9, and maintain good properties in five cycles.
- Thiacalix[4]arene,
- Synthesis,
- Polymer,
- Dye adsorption
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