Citation: Feng-Hua Zhao, Ruo-Jin Liu, Xiao-Yan Yu, Cheng-Chun Tang, Xiong-Wei Qua, Qing-Xin Zhang. Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer[J]. Chinese Chemical Letters, ;2015, 26(6): 727-729. doi: 10.1016/j.cclet.2015.03.025 shu

Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer

Feng-Hua Zhao ^a ,
Ruo-Jin Liu ^a ,
Xiao-Yan Yu ^a,b,, ,
^c ,
Cheng-Chun Tang ^b ,
Xiong-Wei Qua ^b ,
Qing-Xin Zhang ^a,b,,

1.
a Institute of Polymer Science and Engineering, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China;
2.
b Key Lab for Micro-and Nano-Scale Boron Nitride Materials in Hebei Province, Hebei University of Technology, Tianjin 300130, China;
3.
c National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba-city, Ibaraki 305-0047, Japan

Corresponding author: Xiao-Yan Yu, Qing-Xin Zhang,
Received Date: 1 December 2014
Available Online: 12 March 2015
Fund Project:

A novel naphthyl-based self-catalyzed phthalonitrile monomer was prepared via nucleophilic displacement reaction. The structure was characterized by Fourier infrared spectrum (FT-IR) and nuclear magnetic resonance (¹H NMR). The polymerization mechanism was explored. Thermal properties were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), which demonstrated self-promoted behavior and excellent heat resistance.
- Phthalonitrile polymer,
- Self-catalyzed,
- Thermal properties,
- Heat resistance
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