Citation: Long Qin, Peng-Fei Duan, Ming-Hua Liu. Interfacial assembly and host-guest interaction of anthracene-conjugated L-glutamate dendron with cyclodextrin at the air/water interface[J]. Chinese Chemical Letters, ;2014, 25(4): 487-490. doi: 10.1016/j.cclet.2013.12.019 shu

Interfacial assembly and host-guest interaction of anthracene-conjugated L-glutamate dendron with cyclodextrin at the air/water interface

1.
Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface, and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Ming-Hua Liu,
Received Date: 24 October 2013
Available Online: 25 November 2013
Fund Project:

The interfacial assembly of photo-induced dimerization of atypical anthracene-containing amphiphilic dendron and host-guest interaction with γ-cyclodextrin has been investigated. It has been proved that even without long alkyl chain the amphiphilic dendron could still form stable Langmuir monolayer at the air/water interface. Through the host-guest interaction, γ-cyclodextrin can be used to encapsulate two headgroups of amphiphilic dendron in the antiparallel direction. However, the formed host-guest complex was sensitive to the surface pressure. Slight compression of surface pressure led amphiphilic dendron to reassemble into nanofibers through the strong π-π stacking between headgroups. On the other hand, under in situ irradiation, the amphiphilic dendron was stabilized in the cavity of gcyclodextrin through headgroup dimerization and the host-guest complex further irregularly aggregated to nanoparticles. Meanwhile, γ-cyclodextrin, as a silencer, blocked the supramolecular chirality transfer. Our conclusion was demonstrated through UV/vis, FT-IR, CD spectrum and AFM images, respectively.
- Dendron,
- γ-Cyclodextrin,
- Host-guest complex,
- π-π stacking,
- Supramolecular assembly
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