Citation: Shi Chao Xu, Bing Cheng Hu, Wei You Zhou, Cheng Guo Sun, Zu Liang Liu. The synthesis, self-assembly and electrocatalytic property of a novel disulphide derivatised cobalt(Ⅱ) deuteroporphyrin[J]. Chinese Chemical Letters, ;2012, 23(2): 157-160. doi: 10.1016/j.cclet.2011.11.011 shu

The synthesis, self-assembly and electrocatalytic property of a novel disulphide derivatised cobalt(Ⅱ) deuteroporphyrin

School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received Date: 22 August 2011

Fund Project: This project is financially supported by Jiangsu Natural Science Foundation (No. BK2009386) and NUST research founding (No. 2010GJPY043).

A novel disulphide derivatised deuteroporphyrin 2, 7, 12, 18-tetramethyl-13, 17-(propionylaminoethyldithioethyl amino-formylethyl)-29, 34-bis-(methoxyformyl)porphyrin (PDTEP, 3) and its cobalt(Ⅱ) complex (Co(Ⅱ)PDTEP, 4) were conveniently synthesized. The disulphide functional group of 4 allowed its stable immobilization on gold electrodes. The modified electrode was characterized by IR and confirmed electrochemically and showed good stability and catalytic activity toward the electro-catalyzed reduction of hydrogen peroxide.
- Deutorporphyrin,
- Disulphide derivate,
- Electrocatalysis,
- Self-assembly
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