Citation: Bahador Karami, S. Jafar Hoseini, Shaghayegh Nikoseresht, Saeed Khodabakhshi. Fe₃O₄ nanoparticles:A powerful and magnetically recoverable catalyst for the synthesis of novel calix[4]resorcinarenes[J]. Chinese Chemical Letters, ;2012, 23(2): 173-176. doi: 10.1016/j.cclet.2011.11.005 shu

Fe₃O₄ nanoparticles:A powerful and magnetically recoverable catalyst for the synthesis of novel calix[4]resorcinarenes

a Department of Chemistry, Yasouj University, Yasouj 75918-74831, P. O. Box 353, Iran;
b Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran 75817, Iran

Received Date: 25 August 2011

A simple synthesis of novel and known calix[4]resorcinarenes derivatives has been achieved by the condensation of resorcinol and different aromatic arylaldehyde in the presence of catalytic amounts of Fe₃O₄ nanoparticles under solvent-free conditions. The experimental conditions have been thoroughly optimized and established, allowing significant rate enhancements and good to excellent yields. The reactions can be run safely without using any toxic organic solvents under mild reaction conditions. The Fe₃O₄ nanoparticles were characterized by powdered x-ray diffraction (XRD), transmission electron microscopy (TEM) and FT-IR spectroscopy.
- Fe₃O₄ nanoparticles,
- Calix[4]resorcinarenes,
- Resorcinol,
- Arylaldehyde
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