Citation: Yang Wei Huang, Nan Yan Fu. Synthesis and properties of a novel squaraine dye modified by ferrocene[J]. Chinese Chemical Letters, ;2011, 22(11): 1301-1304. doi: 10.1016/j.cclet.2011.05.039 shu

Synthesis and properties of a novel squaraine dye modified by ferrocene

Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory and Breeding Base Co-developed by Province and Ministry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Received Date: 16 March 2011

Fund Project: The authors are grateful to the National Natural Science Foundation of China (No.20702005) and the Fujian Provincial Natural Science Foundation of China (No.2008J0148).

A novel squaraine dye (SQ) modified by ferrocene has been synthesized through (E)-l-dodecyl-2-ferrocenyl vinyl-1H-pyrrole and squaric acid. The molecular structure of SQ was characterized by ¹H NMR, ¹³C NMR, MS and elemental analysis. SQ is high soluble in common solvents. The maximum absorptions of SQ in different solvents are in the range of 708-734 nm, exhibiting positive solvatochromism with increasing solvent polarity. The optical and electrical properties of SQ indicate that it is a promising electron donor material for bulk-heterojunction organic solar cell.
- Squaraine dye,
- Ferrocene,
- Bulk-heterojunction organic solar cell
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