Citation: Lu Zhang, Juan Du, Li Hua Yuan, Dong Zhang, Gui Ping Dan, Yuan You Yang, Wen Feng. Synthesis of novel calixcrown derivatives with selective complexation towards cesium ions[J]. Chinese Chemical Letters, ;2011, 22(3): 284-287. doi: 10.1016/j.cclet.2010.10.004 shu

Synthesis of novel calixcrown derivatives with selective complexation towards cesium ions

Lu Zhang ^a, ,
Juan Du ^a ,
Li Hua Yuan ^a ,
Dong Zhang ^b ,
Gui Ping Dan ^b ,
Yuan You Yang ^a ,
Wen Feng ^a

a Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, China;
b Institute of Nuclear Physics and Chemistry, CAEP, Mianyang 621900, China

Received Date: 11 June 2010

Fund Project: This work was financially supported by Institute of Nuclear Physics and Chemistry of CAEP (No. HG2008061), and Analytical & Testing Center of Sichuan University for NMR analysis.

A series of novel calix[4]arenecrown-6 derivatives with an alkenyl loop of various sizes 5-8 were synthesized via intramolecular ring closing olefin metathesis and characterized by ¹H NMR, ¹³C NMR and ESI-HRMS. Their complexation property towards cesium ion was studied by ¹H NMR technique. Two-phase extraction of alkali metal ions using UV-vis spectroscopy revealed remarkably different extractabilities. These results indicate that the complexation capacities towards cesium ions can be tuned and controlled through cooperative regulation of the strain of the loop and conformational change of calixcrown skelton.
- Calixcrowns,
- Olefin metathesis,
- Cesium ions,
- Extraction
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