Citation: Hui Jing Zhang, Yong Gang Hu, Yong Qian Wang, Jie Zhang. Electrogeneration of ferrate (Ⅵ) in low concentration NaOH solution for flow-injection-chemiluminescence detection[J]. Chinese Chemical Letters, ;2010, 21(8): 951-954. doi: 10.1016/j.cclet.2010.02.025 shu

Electrogeneration of ferrate (Ⅵ) in low concentration NaOH solution for flow-injection-chemiluminescence detection

a School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;
b State Key Laboratory of Agricultural Microbiology, College of Life Science and Technology, Huazhong Agricultural University, Wuhan 430070, China;
c College of Environmental Science & Technology, Huangshi Institute of Technology, Huangshi 435003, China

Received Date: 26 November 2009

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20005005), Hubei BiomassResource Chemistry and Environmental Biotechnology Key Laboratory (Wuhan University) (No. HBRCEBL2007004), and the Opening Foundation of State Key Laboratory of Agricultural Microbiology (No. AML-200905).

The possibility of direct analytical applications of ferrate (Ⅵ) solution,which was freshly electrogenerated in low-concentration NaOH electrolyte,was studied by a flow-injection-chemiluminescence (FI-CL) system.It was found that some inorganic ions,organic molecule and biomolecule could enhance the chemiluminescence emission caused by ferrate (Ⅵ)-Iuminol reaction.Ⅴ (Ⅴ),Ca (Ⅱ),Mg (Ⅱ),phloroglucinol,and bovine hemoglobin (Hb) chosen as samples were successfully detected by this developed method.The analytical characteristics of the system for the analytes determination including linear ranges,correlation coefficients,limits of detection combined with FI analysis were studied.
- Chemiluminescence,
- Flow-injection analysis,
- Ferrate (Ⅵ)
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