Citation: Xin Du, Xiu Juan Feng, Ying Liu, Ren He, Ming Bao. Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd (PH₂PCH₂CH₂)₂ as a precatalyst[J]. Chinese Chemical Letters, ;2010, 21(6): 641-645. doi: 10.1016/j.cclet.2010.01.042 shu

Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd (PH₂PCH₂CH₂)₂ as a precatalyst

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China

Received Date: 13 November 2009

Fund Project: We are grateful to the National Natural Science Foundation of China (No. 20603005) for financial support. This work was partly supported by the program for Changjiang Scholars and Innovative Research Teams in Universities (No. IRT0711).

Suzuki reaction of bromoallenes with arylboronic acids was successfully performed by using an air-stable hemilabile P-O coordinated cyclopalladated complex Pd(PH₂PCH₂CH₂)₂ as a precatalyst, and the corresponding coupling products were obtained in satisfactory to excellent yields. All products are unknown compounds which were characterized by ¹H NMR, ¹³C NMR, IR, and HRMS.
- Suzuki reaction,
- Bromoallene,
- Palladium complex
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