Citation: Cheng Hui Sun, Xin Qi Zhao, Yu Chuan Li, Si Ping Pang. Synthesis of two new cage molecules containing trinitromethyl group[J]. Chinese Chemical Letters, ;2010, 21(5): 572-575. doi: 10.1016/j.cclet.2009.12.001 shu

Synthesis of two new cage molecules containing trinitromethyl group

School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081, China

Received Date: 18 September 2009

Fund Project: We are grateful to the National Natural Science Foundation of China (No.20772011) and the Basic Research Foundation of Beijing Institute of Technology (No. 3090050320906) for financial support for this work.

Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, ¹H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.
- Cage compound,
- Trinitromethyl group,
- Synthesis,
- X-ray crystal structure
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