Citation:
Ali Reza Kiasat, Rashid Badri, Soheil Sayyahi. A facile and convenient method for synthesis of alkyl thiocyanates under homogeneous phase transfer catalyst conditions[J]. Chinese Chemical Letters,
;2008, 19(11): 1301-1304.
doi:
10.1016/j.cclet.2008.07.019
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A simple and environmentally friendly method is described for the efficient conversion of alkyl halide to alkyl thiocyanate using tetrabutylammonium bromide (TBAB) as a phase transfer catalyst.The reactions occur in water and furnish the corresponding alkyl thiocyanate in high yields.No evidence for the formation of isothiocyanates as by-product of the reaction was observed and the products were obtained in pure form without further purification.
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