Citation: Pu Zhang, Zhi Xin Guo, Shuang Lv. Synthesis and aggregation properties of amphiphilic mono and bisadducts of fullerene in aqueous solution[J]. Chinese Chemical Letters, ;2008, 19(9): 1039-1042. doi: 10.1016/j.cclet.2008.06.017 shu

Synthesis and aggregation properties of amphiphilic mono and bisadducts of fullerene in aqueous solution

a Department of Chemistry, Renmin University of China, Beijing 100872, China;
b Department of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Received Date: 10 March 2008

Fund Project: This research was sponsored by the National Natural Science Foundation of China (No. 20503039) and the Scientific Research Starting Foundation of Department of Chemistry, Renmin University of China.

amphiphilic[60]fullerene monoadduet TPF and bisadducts BTPF were synthesized and well-characterized. Their aggregation properties in aqueous solution was investigated by UV-vis and TEM methods. In aqueous solution, monoadduct TPF forms irregularly shaped and some rod-like aggregates, whereas bisadducts BTPF gives spherical aggregates with diameters of 50-150 nm. It indicated that the aggregation properties of amphiphilic fullerene derivatives depend on the number of hydrophilic appendage on the C₆₀ cage.
- Fullerene,
- Aggregation,
- Amphiphilic
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