Citation: Xin Wang, Juan Shen, Jin Cui Wu, Min Fang, Hong Yao Xu. Preparation and property of a novel soluble electron transport POSS-based hybrid material[J]. Chinese Chemical Letters, ;2008, 19(6): 634-638. doi: 10.1016/j.cclet.2008.04.016 shu

Preparation and property of a novel soluble electron transport POSS-based hybrid material

Xin Wang ^a,c, ,
Juan Shen ^a ,
Jin Cui Wu ^a ,
Min Fang ^a ,
Hong Yao Xu ^a,b

a School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China;
b College of Material Science and Engineering & State Key Laboratory of Chemical Fibers and Polymeric Materials, Donghua University, Shanghai 201620, China;
c School of Chemistry, Chizhou University, Chizhou 247000, China

Received Date: 19 December 2007

Fund Project: Program for New Century Excellent Talents in University (No. NCET-04-0588)This research was financially supported by the National Natural Science Fund of China (Nos. 90606011 and 50472038)

A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl₃, toluene, C₂H₄Cl₂, and THF. Its structures and properties were characterized and evaluated with FTIR, ¹H NMR, ¹³C NMR, ²⁹Si NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability.
- CV,
- Electron transport,
- Oxadiazole,
- POSS,
- Thermal stability
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