Citation:
Xin Wang, Juan Shen, Jin Cui Wu, Min Fang, Hong Yao Xu. Preparation and property of a novel soluble electron transport POSS-based hybrid material[J]. Chinese Chemical Letters,
;2008, 19(6): 634-638.
doi:
10.1016/j.cclet.2008.04.016
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A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl3, toluene, C2H4Cl2, and THF. Its structures and properties were characterized and evaluated with FTIR, 1H NMR, 13C NMR, 29Si NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability.
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Keywords:
- CV,
- Electron transport,
- Oxadiazole,
- POSS,
- Thermal stability
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