Citation: Jian Quan Fan, La Sheng Jiang, Min Zhang, Na Wei, Ya Hui Feng, Shu Juan Han, Hui Wang. Synthesis of novel biscrown ethers with rigid cis/trans ethylene bridge[J]. Chinese Chemical Letters, ;2008, 19(5): 513-517. doi: 10.1016/j.cclet.2008.03.002 shu

Synthesis of novel biscrown ethers with rigid cis/trans ethylene bridge

School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China

Received Date: 29 October 2007

Fund Project: This work is supported in part by National Natural Science Foundation of China (No.20672038) and Natural Science Foundation of Guangdong Province (No.5005934).

Two novel biscrown ethers with rigid cisltrans ethylene linker were synthesized v/a Wittig reaction in high yield (about 80%).Their pure cis/trans-isomers were obtained by column chromatography separation. And their structure/configuration was confirmedby ¹H NMR, ¹³C NMR, ESI mass spectrum, elemental analysis and UV-vis spectra.
- Biscrown ethers,
- Synthesis,
- Characterization,
- Cis/trans configuration
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