Citation: Yu Min Han, Zhi Li, Jiu Li Luo. Temperature waves in chemical reaction-diffusion-heat conduction systems with two ends respectively subject to Dirichlet and no-flux conditions[J]. Chinese Chemical Letters, ;2007, 18(11): 1427-1430. doi: 10.1016/j.cclet.2007.09.021 shu

Temperature waves in chemical reaction-diffusion-heat conduction systems with two ends respectively subject to Dirichlet and no-flux conditions

Institute of Chemical Physics, College of Chemistry, Sichuan University, Chengdu 610064, China

Received Date: 8 May 2007

Fund Project: The work is supported by the Doctoral Program Foundation of Ministry of Education of China (No.20050610012).

Taking the Lindemann model as a sample system in which there exist chemical reactions, diffusion and heat conduction, we found the theoretical framework of linear stability analysis for a unidimensional nonhomogeneous two-variable system with one end subject to Dirichlet conditions, while the other end no-flux conditions. Furthermore, the conditions for the emergence of temperature waves are found out by the linear stabiliy analysis and verified by a diagram for successive steps of evolution of spatial profile of temperature during a period that is plotted by numerical simulations on a computer. Without doubt, these results are in favor of the heat balance in chemical reactor designs.
- Temperature waves,
- Lindemann model,
- Chemical reaction-diffusion-heat conduction
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