Citation: Juan Li, Song Lin Zhang, Chuan Zhou Tao, Yao Fu, Qing Xiang Guo. Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine[J]. Chinese Chemical Letters, ;2007, 18(9): 1033-1036. doi: 10.1016/j.cclet.2007.07.028 shu

Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine

Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Received Date: 18 April 2007

Fund Project: This research was supported by the NNSFC (No.20472079).

Cu-catalyzed cross coupling between phosphinic amides and aryl halides was accomplished for the first time by using (±)-trans-cyclohexane-1, 2-diamine as the ligand. This reaction provided a novel approach for synthesizing arylated phosphinic amides. Both kinetic measurement and theoretical calculation indicated that phosphinic amides were much less reactive than amides by about 10times in Cu-catalyzed cross coupling.
- Phosphinic amide,
- Copper,
- Catalyst,
- Cross coupling
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