Citation: Behzad Haghighi, Mohammad Reza Hussaindokht, Mohammad Reza Bozorgmehr, Naser Seyed Matin. Joule-Thomson inversion curve prediction by using equation of state[J]. Chinese Chemical Letters, ;2007, 18(9): 1154-1158. doi: 10.1016/j.cclet.2007.07.002 shu

Joule-Thomson inversion curve prediction by using equation of state

a Thermodynamic and Transport Properties Research Laboratory Department of Chemistry(T & TPRL), Birjand University, Birjand 97175-615, Iran;
b Department of Chemistry, Faculty of Sciences, Ferdowsi University, Mashad 91779-1436, Iran;
c Department of Chemistry, Faculty of Sciences, Islamic Azad University of Mashhad, Mashad, Iran;
d National Iranian Oil Company(NIOC), Research Institute of Petroleum Industry(RIPI), Tehran 18745-4391, Iran

Received Date: 14 March 2007

Fund Project: Authors would like to thank the University authorities for providing partly the necessary facilities to carry out the work.One of us (B.H.) would like to thank Prof.U.K.Dieters for stimulating talks,instructive discussions,and sharing of useful information at the ICCT/IUPAC (July 28-August 02,2002) biannual meeting.

In this paper five equations of state are tested for checking their ability to predict the Joule-Thomson inversion curve. These five equations of state are:Mohsennia-Modarres-Mansoori (MMM), Ji-Lemp (JL), modified Soave-Redlich-Kwang (SRK) equation of state by Graboski (MSRK1), modified SRK equation of state by Peneloux and Rauzy (MSRK2), and modified Peng-Robinson (PR) equation of state by Rauzy (PRmr). The investigated equations of state give good prediction of the low-temperature branch of the inversion curve, except for MMM equation of state. The high-temperature branch and the peak of the inversion curve have been observed, in general, to be sensitive to the applied equation of state. The values of the maximum inversion temperature and maximum inversion pressure are calculated for each component used in this work.
- Equation of state,
- Joule-Thomson coefficient,
- Inversion curve
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