Citation: Hong Kui Zhang, Wing Hong Chan, Albert W. M. Lee, Ping Fang Xia, Wai Yeung Wong. A novel reductive ring-opening reaction of isoxazolidine to form functionalized 1, 3-aminoalcohol[J]. Chinese Chemical Letters, ;2007, 18(6): 629-632. doi: 10.1016/j.cclet.2007.04.001 shu

A novel reductive ring-opening reaction of isoxazolidine to form functionalized 1, 3-aminoalcohol

a Department of Chemistry, Xiamen University, Xiamen 361005, China;
b Department of Chemistry, Hong Kong Baptist University, Kowloog Tong, Hong Kong

Received Date: 13 November 2006

Reductive cleavage of the N-O bond of isoxazolidine ring with catalytic hydrogenation over Raney nickel was described.Bicyclic isoxazolidines could be effectively converted into the corresponding 1, 3-amino-alcohol possessing a sultone or sultam moiety with high conversion and yield when the hydrogenation was catalyzed by freshly prepared Raney nickel under a pressure of 40 psi in the presence of triethylamine.
- Isoxazolidine,
- Hydrogenation,
- Raney nickel,
- 1, 3-Amino-alcohol
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