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Citation: Yun Wang, Meng Huo, Min Zeng, Lei Liu, Qi-Quan Ye, Xi Chen, Dan Li, Liao Peng, Jin-Ying Yuan. CO2-responsive Polymeric Fluorescent Sensor with Ultrafast Response[J]. Chinese Journal of Polymer Science, ;2018, 36(12): 1321-1327. doi: 10.1007/s10118-018-2167-y shu

CO2-responsive Polymeric Fluorescent Sensor with Ultrafast Response

  • Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China

  • Corresponding author: Jin-Ying Yuan, yuanjy@mail.tsinghua.edu.cn
  • Received Date: 7 May 2018
    Revised Date: 27 May 2018
    Accepted Date: 28 May 2018
    Available Online: 11 July 2018

  • Response speed is one of the most important evaluation criteria for CO2 sensors. In this work, we report an ultrafast CO2 fluorescent sensor based on poly[oligo(ethylene glycol) methyl ether methacrylate]-b-poly[N,N-diethylaminoethyl methacrylate-r-4-(2-methylacryloyloxyethylamino)-7-nitro-2,1,3-benzoxadiazole] [POEGMA-b-P(DEAEMA-r-NBDMA)], in which DEAEMA units act as the CO2-responsive segment and 4-nitrobenzo-2-oxa-1,3-diazole (NBD) is the chromophore. The micelles composed of this copolymer could disassemble in 2 s upon CO2 bubbling, accompanying with enhanced fluorescence emission with bathochromic shift. Furthermore, the quantum yield of the NBD chromophore increases with both the CO2 aeration time and the NBD content. Thus we attribute the fluorescent enhancement to the inhibition of the photo-induced electron transfer between unprotonated tertiary amine groups and NBD fluorophores. The sensor is durable although it is based on " soft” materials. These micellar sensors could be facilely recycled by alternative CO2/Ar purging for at least 5 times, indicating good reversibility.
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