Citation: Zi-Bo Wei, Yang Zhao, Chao Wang, Shigenori Kuga, Yong Huang, Min Wu. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite[J]. Chinese Journal of Polymer Science, ;2018, 36(12): 1361-1367. doi: 10.1007/s10118-018-2160-5 shu

Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite

Zi-Bo Wei ^1,2 ,
Yang Zhao ^1,, ,
Chao Wang ¹ ,
Shigenori Kuga ¹ ,
Yong Huang ¹ ,
Min Wu ^1,,

a.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Yang Zhao, yzhao@mail.ipc.ac.cn Min Wu, wumin@mail.ipc.ac.cn
Received Date: 23 March 2018
Revised Date: 2 May 2018
Accepted Date: 19 May 2018
Available Online: 14 June 2018

Multilayer graphene was prepared by mechanical exfoliation of natural graphite with dioctyl phthalate (DOP) as milling medium without solvent. The obtained mixture could be directly mixed with poly(vinyl chloride) (PVC) for melt-forming, with DOP acting as plasticizer and graphene acting as conductive filler for antistatic performance. The composite showed surface resistance of 2.5 × 10⁶ Ω/□ at 1 wt% carbon additive, significantly lower than approx. 7 wt% of raw graphite required for achieving the same level. This value is low enough for practical antistatic criterion of 3 × 10⁸ Ω/□. The effect of filler addition on mechanical performance was minimal, or even beneficial for the milled carbon in contrast to the case of raw graphite.
- Antistatic composite,
- Poly(vinyl chloride),
- Graphene,
- Mechanical exfoliation,
- Electrical property
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