Citation: Wei Wang, Fei Gao, Yuan Yao, Shao-Liang Lin. Directional Photo-manipulation of Self-assembly Patterned Microstructures[J]. Chinese Journal of Polymer Science, ;2018, 36(3): 297-305. doi: 10.1007/s10118-018-2087-x shu

Directional Photo-manipulation of Self-assembly Patterned Microstructures

Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Shao-Liang Lin, slin@ecust.edu.cn
Received Date: 28 September 2017
Accepted Date: 6 November 2017
Available Online: 20 December 2017

Highly intricate surface architectures derived from patterned polymer microstructures have received increasing concern in recent years. Directional photo-manipulation (DPM) of azopolymers is one of the effective strategies to tune the patterned polymer microstructures through directional mass migration (DMM) upon polarized light illumination. In this feature article, we emphasize the latest advances of DPM on azopatterns created by self-assembly. The mechanism of DMM, the photo-manipulation performance, and functions of manipulated patterns are introduced in sequence. As presented, DPM can manipulate the as-prepared microstructures feasibly by taking the advantages of non-contacting and nondestructive characters. Moreover, the challenges and opportunities of DPM strategy are discussed in conclusion.
- Self-assembly,
- Directional photo-manipulation,
- Surface patterning,
- Azopolymer
1. [1]
  Li L., Köpf M. H., Gurevich S. V., Friedrich R., Chi L.. Structure formation by dynamic self-assembly[J]. Small, 2012,8(4):488-503. doi: 10.1002/smll.v8.4
2. [2]
  Nie Z., Kumacheva E.. Patterning furfaces with functional polymers[J]. Nat. Mater., 2008,7(4):277-290. doi: 10.1038/nmat2109
3. [3]
  Huang H., Yi G., Zu X., Zhong B., Luo H.. Patterning of triblock copolymer film and its application for surface-enhanced raman scattering[J]. Chinese J. Polym. Sci., 2017,35(5):623-630. doi: 10.1007/s10118-017-1914-9
4. [4]
  Biswas A., Bayer I. S., Biris A. S., Wang T., Dervishi E., Faupel F.. Advances in top-down and bottom-up surface nanofabrication:Techniques, applications & future prospects[J]. Adv. Colloid Interface Sci., 2012,170(1):2-27.
5. [5]
  Liu X., Yang J., Zha L., Jiang Z.. Self-assembly of hollow PNIPAM microgels to form discontinuously hollow fibers[J]. Chinese J. Polym. Sci., 2014,32(11):1544-1549. doi: 10.1007/s10118-014-1508-8
6. [6]
  Ma H., Hao J.. Ordered patterns and structures via interfacial self-assembly:Superlattices, honeycomb structures and coffee rings[J]. Chem. Soc. Rev., 2011,40(11):5457-5471. doi: 10.1039/c1cs15059f
7. [7]
  Wang D., Möhwald H.. Template-directed colloidal self-assembly-the route to 'top-down' nanochemical engineering[J]. J. Mater. Chem., 2004,14(4):459-468. doi: 10.1039/B311283G
8. [8]
  Li J., Shim J., Deng J., Overvelde J. T., Zhu X., Bertoldi K., Yang S.. Switching periodic membranes via pattern transformation and shape memory effect[J]. Soft Matter, 2012,8(40):10322-10328. doi: 10.1039/c2sm25816a
9. [9]
  Yabu H., Jia R., Matsuo Y., Ijiro K., Yamamoto S., Nishino F., Takaki T., Kuwahara M., Shimomura M.. Preparation of highly oriented nano-pit arrays by thermal shrinking of honeycomb-patterned polymer films[J]. Adv. Mater., 2008,20(21):4200-4204.
10. [10]
  Zhou J., Sheiko S. S.. Reversible shape-shifting in polymeric materials[J]. J. Polym. Sci., Part B:Polym. Phys., 2016,54(14):1365-1380. doi: 10.1002/polb.v54.14
11. [11]
  Hu Y., Guo W., Kahn J. S., Aleman-Garcia M. A., Willner I.. A shape-memory DNA-based hydrogel exhibiting two internal memories[J]. Angew. Chem. Int. Ed., 2016,55(13):4210-4214. doi: 10.1002/anie.201511201
12. [12]
  Wang W., Lin J., Cai C., Lin S.. Optical properties of amphiphilic copolymer-based self-assemblies[J]. Eur. Polym. J., 2015,65:112-131. doi: 10.1016/j.eurpolymj.2015.01.023
13. [13]
  Chen D., Liu H., Kobayashi T., Yu H.. Fabrication of regularly patterned microporous films by self-organization of an amphiphilic liquid-crystalline diblock copolymer in a dry environment[J]. Macromol. Mater. Eng., 2010,295(1):26-31. doi: 10.1002/mame.v295:1
14. [14]
  Li Y., He Y., Tong X., Wang X.. Photoinduced deformation of amphiphilic azo polymer colloidal spheres[J]. J. Am. Chem. Soc., 2005,127(8):2402-2403. doi: 10.1021/ja0424981
15. [15]
  Lee S., Kang H. S., Park J. K.. High-resolution patterning of various large-rea, highly ordered structural motifs by directional photofluidization lithography:Sub-30-nm Line, ellipsoid, rectangle, and circle arrays[J]. Adv. Funct. Mater., 2011,21(10):1770-1778. doi: 10.1002/adfm.201001927
16. [16]
  Lee S., Kang H. S., Park J. K.. Directional photofluidization lithography:Micro/nanostructural evolution by photofluidic motions of azobenzene materials[J]. Adv. Mater., 2012,24(16):2069-2103. doi: 10.1002/adma.201104826
17. [17]
  Yu H., Kobayashi T.. Photoresponsive block copolymers containing azobenzenes and other chromophores[J]. Molecules, 2010,15(1):570-603.
18. [18]
  Xing Y., Lin S., Lin J., He X.. Synthesis, self-assembly and responsive properties of PEG-b-PDMAEMA-b-PMMAzo triblock copolymers[J]. Chinese J. Polym. Sci., 2013,31(5):833-840. doi: 10.1007/s10118-013-1283-y
19. [19]
  Hoersch D.. Let there be light:How to use photoswitchable cross-linker to reprogram proteins[J]. Biochem. Soc. Trans., 2017,45(3):831-837. doi: 10.1042/BST20160386
20. [20]
  Weis P., Wu S.. Light-switchable azobenzene-containing macromolecules:from UV to near infrared[J]. Macromol. Rapid Commun., 2017. doi: 10.1002/marc.201700220
21. [21]
  Goulet-Hanssens A., Utecht M., Mutruc D., Titov E., Schwarz J., Grubert L., Bléger D., Saalfrank P., Hecht S.. Electrocatalytic Z→E isomerization of azobenzenes[J]. J. Am. Chem. Soc., 2017,139(1):335-341. doi: 10.1021/jacs.6b10822
22. [22]
  Zhao, Y.; Ikeda, T. Smart light-responsive materials:Azobenzene-containing polymers and liquid crystals. John Wiley & Sons:2009.
23. [23]
  Wang H., Lee K. M., White T. J., Oates W. S.. Trans-cis and trans-cis-trans microstructure evolution of azobenzene liquid-crystal polymer networks[J]. Macromol. Theory Simul., 2012,21(5):285-301. doi: 10.1002/mats.v21.5
24. [24]
  Bin J., Oates W. S.. A unified material description for light induced deformation in azobenzene polymers[J]. Sci. Rep., 20155. doi: 10.1038/srep14654
25. [25]
  Han M., Morino S., Ichimura K.. Factors affecting in-plane and out-of-plane photoorientation of azobenzene side chains attached to liquid crystalline polymers induced by irradiation with linearly polarized light[J]. Macromolecules, 2000,33(17):6360-6371. doi: 10.1021/ma000347m
26. [26]
  Fang G., Maclennan J., Yi Y., Glaser M., Farrow M., Korblova E., Walba D., Furtak T., Clark N.. Athermal photofluidization of glasses[J]. Nat. Commun., 20134. doi: 10.1038/ncomms2483
27. [27]
  Yu H.. Photoresponsive liquid crystalline block copolymers:From photonics to nanotechnology[J]. Prog. Polym. Sci., 2014,39(4):781-815. doi: 10.1016/j.progpolymsci.2013.08.005
28. [28]
  Yu H.. Recent advances in photoresponsive liquid-crystalline polymers containing azobenzene chromophores[J]. J. Mater. Chem. C, 2014,2(17):3047-3054. doi: 10.1039/C3TC31991A
29. [29]
  Karageorgiev P., Neher D., Schulz B., Stiller B., Pietsch U., Giersig M., Brehmer L.. From anisotropic photo-fluidity towards nanomanipulation in the optical near-field[J]. Nat. Mater., 2005,4(9):699-703. doi: 10.1038/nmat1459
30. [30]
  Gao F., Wang W., Li X., Li L., Lin J., Lin S.. Fabrication of ordered honeycomb amphiphobic films with extremely low fluorine content[J]. J. Colloid Interface Sci., 2016,468(15):70-77.
31. [31]
  Zhang A., Bai H., Li L.. Breathfigure:A nature-inspired preparation method for ordered porous films[J]. Chem. Rev., 2015,115(18):9801-9868. doi: 10.1021/acs.chemrev.5b00069
32. [32]
  Wang W., Du C., Wang X., He X., Lin J., Li L., Lin S.. Directional photomanipulation of breath figure arrays[J]. Angew. Chem. Int. Ed., 2014,53(45):12116-12119. doi: 10.1002/anie.201407230
33. [33]
  Wang W., Yao Y., Luo T., Chen L., Lin J., Li L., Lin S.. Deterministic reshaping of breath figure arrays by directional photomanipulation[J]. ACS Appl. Mater. Interfaces, 2017,9(4):4223-4230. doi: 10.1021/acsami.6b14024
34. [34]
  Kong X., Wang X., Luo T., Yao Y., Li L., Lin S.. Photomanipulated architecture and patterning of azopolymer array[J]. ACS Appl. Mater. Interfaces, 2017,9(22):19345-19353. doi: 10.1021/acsami.7b04273
35. [35]
  Lee S., Shin J., Lee Y. H., Park J. K.. Fabrication of the funnel-shaped three-dimensional plasmonic tip arrays by directional photofluidization lithography[J]. ACS nano, 2010,4(12):7175-7184. doi: 10.1021/nn1017507
36. [36]
  Li C., Wang W., Wang X., Jiang H., Zhu J., Lin S.. Fabrication of porous polymer microspheres by tuning amphiphilicity of the polymer and emulsion-solvent evaporation processing[J]. Eur. Polym. J., 2015,68:409-418. doi: 10.1016/j.eurpolymj.2015.05.011
37. [37]
  Wang Y., Lin S., Zang M., Xing Y., He X., Lin J., Chen T.. Self-assembly and photo-responsive behavior of novel ABC 2-type block copolymers containing azobenzene moieties[J]. Soft Matter, 2012,8(11):3131-3138. doi: 10.1039/c2sm07100b
38. [38]
  Lin S., Wang Y., Cai C., Xing Y., Lin J., Chen T., He X.. Tuning self-assembly and photo-responsive behavior of azobenzene-containing triblock copolymers by combining homopolymers[J]. Nanotechnology, 2013,24(8). doi: 10.1088/0957-4484/24/8/085602
39. [39]
  Wang J., Wang S., Zhou Y., Wang X., He Y.. Fast photoinduced large deformation of colloidal spheres from a novel 4-arm azobenzene compound[J]. ACS Appl. Mater. Interfaces, 2015,7(30):16889-16895. doi: 10.1021/acsami.5b05651
40. [40]
  Li J., Chen L., Xu J., Wang K., Wang X., He X., Dong H., Lin S., Zhu J.. Photoguided shape deformation of azobenzene-containing polymer microparticles[J]. Langmuir, 2015,31(48):13094-13100. doi: 10.1021/acs.langmuir.5b03610
41. [41]
  Kang H. S., Lee S., Lee S. A., Park J. K.. Multilevel micro/nano texturing by three dimensionally controlled photofluidization and its use in plasmonic applications[J]. Adv. Mater., 2013,25(38):5490-5497. doi: 10.1002/adma.201301715
42. [42]
  Choi J., Cho W., Jung Y. S., Kang H. S., Kim H. T.. Direct fabrication of micro/nano-patterned surfaces by verticaldirectional photofluidization of azobenzene materials[J]. ACS Nano, 2017,11(2):1320-1327. doi: 10.1021/acsnano.6b05934
43. [43]
  Sun P. Z., Liu Z., Wang W., Ma L. L., Shen D., Hu W., Lu Y., Chen L., Zheng Z. G.. Light-reconfigured wavebandselective diffraction device enabled by micro-patterning of a photoresponsive self-organized helical superstructure[J]. J. Mater. Chem. C, 2016,4(39):9325-9330. doi: 10.1039/C6TC02443B
44. [44]
  Gao Y., Li A., Gu Z., Wang Q., Zhang Y., Wu D., Chen Y., Ming N., Ouyang S., Yu T.. Fabrication and optical properties of two-dimensional ZnO hollow half-shell arrays[J]. Appl. Phys. Lett., 2007,91(3). doi: 10.1063/1.2759268
45. [45]
  Wiktor P., Brunner A., Kahn P., Qiu J., Magee M., Bian X., Karthikeyan K., LaBaer J.. Microreactor array device[J]. Sci. Rep., 2015,58736. doi: 10.1038/srep08736
46. [46]
  Oscurato S. L., Borbone F., Maddalena P., Ambrosio A.. Light-driven wettability tailoring of azopolymer surfaces with reconfigured three-dimensional posts[J]. ACS Appl. Mater. Interfaces, 2017,9(35):30133-30142. doi: 10.1021/acsami.7b08025
47. [47]
  Phillips K. R., Vogel N., Hu Y., Kolle M., Perry C. C., Aizenberg J.. Tunable anisotropy in inverse opals and emerging optical properties[J]. Chem. Mater., 2014,26(4):1622-1628. doi: 10.1021/cm403812y
48. [48]
  Gu J., Xiao P., Chen J., Zhang J., Huang Y., Chen T.. Janus polymer/carbon nanotube hybrid membranes for oil/water separation[J]. ACS Appl. Mater. Interfaces, 2014,6(18):16204-16209. doi: 10.1021/am504326m
49. [49]
  Pirani F., Angelini A., Frascella F., Rizzo R., Ricciardi S., Descrovi E.. Light-driven reversible shaping of individual azopolymeric micro-pillars[J]. Sci. Rep., 20166. doi: 10.1038/srep31702
50. [50]
  Hong J. C., Park J. H., Chun C., Kim D. Y.. Photoinduced tuning of optical stop bands in azopolymer based inverse opal photonic crystals[J]. Adv. Funct. Mater., 2007,17(14):2462-2469. doi: 10.1002/(ISSN)1616-3028
51. [51]
  Arbabi A., Horie Y., Bagheri M., Faraon A.. Dielectric metasurfaces for complete control of phase and polarization with subwavelength spatial resolution and high transmission[J]. Nat. Nanotechnol., 2015,10(11):937-943. doi: 10.1038/nnano.2015.186
52. [52]
  Zillohu A. U., Abdelaziz R., Homaeigohar S., Krasnov I., Müller M., Strunskus T., Elbahri M.. Biomimetic transferable surface for a real time control over wettability and photoerasable writing with water drop lens[J]. Sci. Rep., 20144. doi: 10.1038/srep07407
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