Citation: Yi-Gang Luan, Xiao-A Zhang, Sheng-Ling Jiang, Jian-Huan Chen, Ya-Fei Lyu. Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide[J]. Chinese Journal of Polymer Science, ;2018, 36(5): 584-591. doi: 10.1007/s10118-018-2025-y shu

Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide

Key Laboratory of Carbon Fiber and Functional Polymers of Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Ya-Fei Lyu, ylu623@hotmail.com
Received Date: 1 August 2017
Accepted Date: 25 August 2017
Available Online: 18 January 2018

A self-healing supramolecular polymer composite (HSP-GO) was designed and prepared via incorporation of modified graphene oxide to hyperbranched polymer by hydrogen-bonding interactions. The polymer matrix based on amino-terminated hyperbranched polymer (HSP-NH₂) was synthesized by carboxylation, Curtius rearrangement, and amination of hydroxyl-terminated hyperbranched polyester (HP-OH), while the modified graphene oxide was prepared by transformation of hydroxyl to isocyanate and further to carbamate ester. Spectroscopic methods were utilized to characterize the obtained polymer composites. Stress-strain test was selected to carefully study the self-healing property of HSP-GO. It is found that a small amount of modified graphene oxide (up to 2 wt%) improves the glass transition temperature (T_g), tensile strength, Young's modulus, and self-healing efficiency of the polymer composites. After healed at room temperature for 10 min, the addition of modified graphene oxide improves the self-healing efficiency to 37% of its original tensile strength. The experiment result shows that the self-healing efficiency is related to the density of hydrogen bonding site and the molecular movement.
- Self-healing,
- Supramolecular polymer,
- Graphene oxide,
- Hydrogen bonding
1. [1]
  Blaiszik B. J., Kramer S. L. B., Olugebefola S. C., Moore J. S., Sottos N. R., White S. R.. Self-healing polymers and composites[J]. Annu. Rev. Mater. Res., 2010,40:179-211. doi: 10.1146/annurev-matsci-070909-104532
2. [2]
  Hager M. D., Greil P., Leyens C., Zwaag S. V. D.. Self-healing materials[J]. Adv. Mater., 2010,22(47):5424-5430. doi: 10.1002/adma.201003036
3. [3]
  Wojtecki R. J., Meador M. A., Rowan S. J.. Using the dynamic bond to access macroscopically responsive structurally dynamic polymers[J]. Nat. Mater., 2011,10(1):14-27. doi: 10.1038/nmat2891
4. [4]
  Chen X., Dam M. A., Ono K., Mal A., Shen H., Nutt S. R., Sheran K., Wudl F.. A thermally re-mendable cross-linked polymeric material[J]. Science, 2002,295(5560):1698-1702. doi: 10.1126/science.1065879
5. [5]
  Burattini S., Greenland B. W., Merino D. H., Weng W., Seppala J., Colquhoun H. M., Hayes W., Mackay M. E., Hamley L. W., Rowan S. J.. A healable supramolecular polymer blend based on aromatic π-π stacking and hydrogen-bonding interactions[J]. J. Am. Chem. Soc., 2010,132(34):12051-12058. doi: 10.1021/ja104446r
6. [6]
  Klukovich H. M., Kean Z. S., Iacono S. T., Craig S. L.. Mechanically induced scission and subsequent thermal remending of perfluorocyclobutane polymers[J]. J. Am. Chem. Soc., 2011,133(44):17882-17888. doi: 10.1021/ja2074517
7. [7]
  Zheng P., Mccarthy T. J.. A surprise from, 1954:siloxane equilibration is a simple, robust, and obvious polymer self-healing mechanism[J]. J. Am. Chem. Soc., 2012,134(4):2024-2027. doi: 10.1021/ja2113257
8. [8]
  Chen X., Wudl F., Mal A. K., Shen H., Nuut S. R.. New thermally remendable highly cross-linked polymeric materials[J]. Macromolecules, 2003,36(6):1802-1807. doi: 10.1021/ma0210675
9. [9]
  Liu F., Li F., Deng G., Chen Y., Zhang B., Zhang J., Liu C. Y.. Rheological images of dynamic covalent polymer networks and mechanisms behind mechanical and self-healing properties[J]. Macromolecules, 2012,45(3):1636-1645. doi: 10.1021/ma202461e
10. [10]
  Ghosh B., Urban M. W.. Self-repairing oxetane-substituted chitosan polyurethane networks[J]. Science, 2009,323(5920):1458-1460. doi: 10.1126/science.1167391
11. [11]
  Burnworth M., Tang L., Kumpfer J. R., Duncan A. J., Beyer F. L., Fiore G. L., Rowan S. J., Weder C.. Optically healable supramolecular polymers[J]. Nature, 2011,472(7343):334-338. doi: 10.1038/nature09963
12. [12]
  Ling J., Rong M. Z., Zhang M. Q.. Effect of molecular weight of PEG soft segments on photo-stimulated self-healing performance of coumarin functionalized polyurethanes[J]. Chinese J. Polym. Sci., 2014,32(10):1286-1297. doi: 10.1007/s10118-014-1522-x
13. [13]
  Lehn J. M.. Dynamers:dynamic molecular and supramolecular polymers[J]. Prog. Polym. Sci., 2005,30:814-831. doi: 10.1016/j.progpolymsci.2005.06.002
14. [14]
  Herbst F., Döhler D., Michael P., Binder W. H.. Self-healing polymers via supramolecular forces[J]. Macromol. Rapid Commun., 2013,34(3):203-220. doi: 10.1002/marc.v34.3
15. [15]
  Cuthbert T. J., Jadischke J. J., Bruyn J. R. D., Ragogna P. J., Gillies E. R.. Self-healing polyphosphonium ionic networks[J]. Macromolecules, 2017,50:5253-5260. doi: 10.1021/acs.macromol.7b00955
16. [16]
  Li Y., Li J., Chen B., Chen Q., Zhang G., Liu S., Ge Z.. Polyplex micelles with thermoresponsive heterogeneous coronasn for prolonged blood retention and promoted gene transfection[J]. Biomacromolecules, 2014,15(8):2914-2923. doi: 10.1021/bm500532x
17. [17]
  Wang C., Zhang G., Liu G., Hu J., Liu S.. Photo-and thermo-responsive multicompartment hydrogels for synergistic delivery of gemcitabine and doxorubicin[J]. J. Control. Release, 2017,259:149-159. doi: 10.1016/j.jconrel.2016.11.007
18. [18]
  Zeng Q., Desai M. S., Jin H. E., Lee J. H., Chang J., Lee S. W.. Self-healing elastin-bioglass hydrogels[J]. Biomacromolecules, 2016,17(8):2619-2625. doi: 10.1021/acs.biomac.6b00621
19. [19]
  Brocorens P., Linares M., Guyardduhayon C., Guillot R., Andrioletti B., Suhr D., Benjiamin I., Lazzaroni R., Bouteiller L.. Conformational plasticity of hydrogen bonded bis-urea supramolecular polymers[J]. J. Phys. Chem. B, 2013,117(17):5379-5386. doi: 10.1021/jp401915y
20. [20]
  van Gemert G. M. L., Peeters J. W., Söntjens S. H. M., Janssen H. M., Bosman A. W.. Self-healing supramolecular polymers in action[J]. Macromol. Chem. Phys., 2012,213:234-242. doi: 10.1002/macp.201100559
21. [21]
  Cordier P., Tournilhac F., Soulie-Ziakovi C., Leibler L.. Self-healing and thermoreversible rubber from supramolecular assembly[J]. Nature, 2008,451(7181):977-980.
22. [22]
  Wang C., Wu H., Chen Z., McDowell M. T., Cui Y., Bao Z.. Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries[J]. Nat. Chem., 2013,5:1042-1048. doi: 10.1038/nchem.1802
23. [23]
  Lopez J., Chen Z., Wang C., Andrews S. C., Cui Y., Bao Z.. The effects of cross-linking in a supramolecular binder on cycle life in silicon microparticle anodes[J]. ACS Appl. Mater. Interfaces, 2016,8:2318-2324. doi: 10.1021/acsami.5b11363
24. [24]
  Tee B. C., Wang C., Allen R., Bao Z.. An electrically and mechanically self-healing composite with pressure-and flexion-sensitive properties for electronic skin applications[J]. Nat. Nanotechnol., 2012,7(12):825-832. doi: 10.1038/nnano.2012.192
25. [25]
  Wang G., Yang J., Park J., Gou X., Wang B., Liu H., Yao J.. Facile synthesis and characterization of graphene nanosheets[J]. J. Phys. Chem. C, 2008,112:8192-8195. doi: 10.1021/jp710931h
26. [26]
  Wang G., Shen X., Yao J., Park J.. Graphene nanosheets for enhanced lithium storage in lithium ion batteries[J]. Carbon, 2009,47:2049-2053. doi: 10.1016/j.carbon.2009.03.053
27. [27]
  Pei S., Cheng H. M.. The reduction of graphene oxide[J]. Carbon, 2012,50(9):3210-3228. doi: 10.1016/j.carbon.2011.11.010
28. [28]
  Wang C., Liu N., Allen R., Tok J. B. H., Wu Y., Zhang F., Chen Y., Bao Z.. A rapid and efficient self-healing thermo-reversible elastomer crosslinked with graphene oxide[J]. Adv. Mater., 2013,25:5785-5790. doi: 10.1002/adma.v25.40
29. [29]
  Li J., Zhang G., Deng L., Zhao S., Gao Y., Jiang K., Sun R., Wong C.. In situ polymerization of mechanically reinforced, thermally healable graphene oxide/polyurethane composites based on Diels-Alder chemistry[J]. J. Mater. Chem. A, 2014,2(48):20642-20649. doi: 10.1039/C4TA04941A
30. [30]
  Xu C., Wu X., Zhu J., Wang X.. Synthesis of amphiphilic graphite oxide[J]. Carbon, 2008,46(2):386-389. doi: 10.1016/j.carbon.2007.11.045
31. [31]
  Zhang A., Yang L., Lin Y., Yan L., Lu H., Wang L.. Self-healing supramolecular elastomers based on the multi-hydrogen bonding of low-molecular polydimethylsiloxanes:synthesis and characterization[J]. J. Appl. Polym. Sci., 2013,129(5):2435-2442. doi: 10.1002/app.38832
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