Citation: Xin-xin Li, Xiao Huo, Hui-jiao Han, Shao-liang Lin. Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer[J]. Chinese Journal of Polymer Science, ;2017, 35(11): 1363-1372. doi: 10.1007/s10118-017-1963-0 shu

Synthesis, Self-assembly and pH Sensitivity of a Novel Fluorinated Triphilic Block Copolymer

a.
Key Laboratory of Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Key Laboratory of Advanced Polymeric Materials, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Xin-xin Li, xinxinli@ecust.edu.cn Shao-liang Lin, slin@ecust.edu.cn
Received Date: 12 March 2017
Revised Date: 7 April 2017
Accepted Date: 11 April 2017

Fund Project: Fundamental Research Funds for the Central Universities B14018Fundamental Research Funds for the Central Universities 222201717001Fundamental Research Funds for the Central Universities WD1616010the National Natural Science Foundation of China 51622301the National Natural Science Foundation of China 51573046

A novel fluorinated triblock copolymer incorporating 2-ethylhexyl methacrylate (EHMA), tert-butyl methacrylate (tBMA) and 1H, 1H, 2H, 2H-perfluorodecyl acrylate (FA) (PEHMA-b-PtBMA-b-PFA) was first synthesized using three successive reversible addition fragmentation chain transfer (RAFT) polymerization and the subsequent hydrolyzing at acidic condition. The as-fabricated triblock copolymer exhibited an interesting morphology evolution from the multi-compartment rod-like structure to spherical structure along with the addition of a selective solution. At the same time, a visible phase separation domain could be seen in the core area due to the existence of fluorocarbon segments. Furthermore, the self-assembly behavior of the triphilic copolymer at different pH was also verified by transmission electron microscopy, as well as the dynamic light scattering. These stimuli-responsive multi-compartment nanostructures may have potential applications in drug delivery.
- Triphilic block copolymer,
- Self-assembly,
- pH sensitivity,
- Fluorinated copolymer,
- Multi-compartment structure
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1.
沈阳化工大学材料科学与工程学院沈阳 110142