Citation: Rafieh-Sadat Norouzian, Moslem M. Lakouraj, Ehsan N. Zare. Novel Conductive PANI/Hydrophilic Thiacalix[4]arene Nanocomposites：Synthesis, Characterization and Investigation of Properties[J]. Chinese Journal of Polymer Science, ;2014, 32(2): 218-229. doi: 10.1007/s10118-014-1402-4 shu

Novel Conductive PANI/Hydrophilic Thiacalix[4]arene Nanocomposites：Synthesis, Characterization and Investigation of Properties

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Polymer Chemistry Research Laboratory, Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar 47416-95447, Iran

Corresponding author: Moslem M. Lakouraj,
Received Date: 13 May 2013
Revised Date: 30 June 2013

Nanocomposites of polyaniline (PANI) and the macrocycle thiacalix[4]arene tetra sulfonate (TCAS) were successfully synthesized in feed ratios of 1:0.25, 1:0.50 and 1:0.75 by three prevail synthetic methods, i.e. in situ polymerization, emulsion polymerization and solution casting technique. The structures of the nanocomposites were confirmed by FTIR, UV-Vis, XRD, SEM, and TEM techniques. The conductivity was measured by a four probe method. The conductivity was recorded to be as high as 10510-2 Scm-1 for the nanocomposite with a nanometer size structure and homogeneously distributed morphology. The electroactivity of the nanocomposites was approved by cyclic voltammetry (CV) and impedance spectroscopy technique (EIS). The antioxidant ability and thermal property of the composites were further studied. Preliminary studies have evidenced the production of conductive nanocomposites with good thermal property and relatively good solubility in N-methyl 2-pyrrolidone (NMP), with the antioxidant activity reaching up to 80%.
- Thiacalix[4]arene,
- Nanocomposite,
- Polyaniline,
- Conductivity,
- Antioxidant
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沈阳化工大学材料科学与工程学院沈阳 110142