Citation:
Hong-ying Zhao, Jing-bo Zhao, Hao Li, Tong Zhao. Preparation and Characterization of Polyborosiloxanes and Their Blends with Phenolic Resin as Shapeable Ceramic Precursors[J]. Chinese Journal of Polymer Science,
;2014, 32(2): 187-196.
doi:
10.1007/s10118-014-1393-1
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Two polyborosiloxanes (PBSis) with char yield up to 74.13% at 800 ℃ were synthesized by the direct polycondensation of boric acid with phenyltrimethoxysilane in diglyme. The PBSis were characterized by gel permeation chromatography, IR spectroscopy as well as 1H-, 29Si- and 11B-NMR. PBSi modified phenol-formaldehyde resins (PBSi/PFs) were prepared at different PBSi/PF mass ratios and were cured at 150 ℃. The PBSi/PFs were characterized by IR spectroscopy, scanning electron microscopy, thermogravimetric analysis and tensile test. The results revealed that the cured PBSi/PFs had sea-island morphology and higher char yield than the common PF. PBSi/PF blend with PBSi/PF mass ratio of 0.4:1 had char yield up to 70.83% at 800 ℃. The PBSi/PFs had tensile strength similar to PF. The ceramization of PBSi/PFs was also studied. The silicon boron oxycarbide (SiBOC) ceramics formed were characterized by IR spectroscopy and elemental analysis. This method provided a valuable way to prepare easily shapeable polymer blends as ceramic precursors.
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