引用本文:
Zhi Qiang WANG, Shi Wei LU, He Fu GUO, Ning Hai HU. CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)2ZrC1(α-C10H7COO)[J]. Chinese Chemical Letters,
1991, 2(7): 557-560.
Citation: Zhi Qiang WANG, Shi Wei LU, He Fu GUO, Ning Hai HU. CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)2ZrC1(α-C10H7COO)[J]. Chinese Chemical Letters, 1991, 2(7): 557-560.
Citation: Zhi Qiang WANG, Shi Wei LU, He Fu GUO, Ning Hai HU. CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)2ZrC1(α-C10H7COO)[J]. Chinese Chemical Letters, 1991, 2(7): 557-560.
CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)2ZrC1(α-C10H7COO)
摘要:
(MeCp)2ZrCl(α-C10H7COO) has five-coordinate bent zirconocene in which the α-naphthoyloxy is a bidentate ligand(Zr-O 2.317(2), 2.260(2)ÅZr-Cl 2.521(1)ÅZr-C 2.480-2.550ÅZr-cent-CH3C5H4 2.217, 2.23OA;Cl-Zr-O1 134.8(1)0;Cl-Zr-O2 78.6(1)O;O1-Zr-O2 56.3(1)O).
English
CRYSTAL STRUCTURE OF FIVE-COORDINATE ZIRCONOCENE COMPLEX (MeCp)2ZrC1(α-C10H7COO)
Abstract:
(MeCp)2ZrCl(α-C10H7COO) has five-coordinate bent zirconocene in which the α-naphthoyloxy is a bidentate ligand(Zr-O 2.317(2), 2.260(2)ÅZr-Cl 2.521(1)ÅZr-C 2.480-2.550ÅZr-cent-CH3C5H4 2.217, 2.23OA;Cl-Zr-O1 134.8(1)0;Cl-Zr-O2 78.6(1)O;O1-Zr-O2 56.3(1)O).
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