Synthesis of Schiff Base Calix[4]arene Crowns

Xiao Bing WAN Chuan Ming JIN Xun GUO Guo Yuan LU

引用本文: Xiao Bing WAN,  Chuan Ming JIN,  Xun GUO,  Guo Yuan LU. Synthesis of Schiff Base Calix[4]arene Crowns[J]. Chinese Chemical Letters, 2002, 13(8): 699-700. shu
Citation:  Xiao Bing WAN,  Chuan Ming JIN,  Xun GUO,  Guo Yuan LU. Synthesis of Schiff Base Calix[4]arene Crowns[J]. Chinese Chemical Letters, 2002, 13(8): 699-700. shu

Synthesis of Schiff Base Calix[4]arene Crowns

摘要: This letter reports the synthesis of Schiff base calix[4]arene crowns containing m-xylylene phenol subunit, in which calix[4]arene Schiff base crowns 2a, 2b and 2c were formed by 1:1 condensation of calix[4]arene diamine 1 with dialdehydes (2, 6-diformyl-4-chlorophenol 3a, 2, 6-diformyl-4-methylphenol 3b, 2, 6-diformyl-4-tert-butylphenol 3c) under high dilute condition in refluxing anhydrous ethanol in 65-70% yield.

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  • 收稿日期:  2001-09-17
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