Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene

Hong Yao Xu Xin Wang Jin Cui Wu

引用本文: Hong Yao Xu,  Xin Wang,  Jin Cui Wu. Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene[J]. Chinese Chemical Letters, 2008, 19(2): 141-145. doi: 10.1016/j.cclet.2007.11.004 shu
Citation:  Hong Yao Xu,  Xin Wang,  Jin Cui Wu. Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene[J]. Chinese Chemical Letters, 2008, 19(2): 141-145. doi: 10.1016/j.cclet.2007.11.004 shu

Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene

  • 基金项目:

    This research is financially supported by the National Natural Science Fund of China (Nos. 90606011 and 50472038) and Program for New Century Excellent Talents in University of China (No. NCET-04-0588).

摘要: A novel high molecular weight functional polyacetylene bearing oxadiazole group as a pendant, poly{4-[2-(4-octoxyphenyl)-1, 3, 4-oxadiazolyl]-benzenyloxypropynylene}, was synthesized by[Rh (nbd) Cl]2-Et3N catalyst.The polymer was soluble in common organic solvents such as CHCl3 and THE The structures and properties of monomer and polymer were characterized and evaluated with FTIR, NMR, UV, TGA, GPC, and CV, respectively.The results show that the polymer possesses high thermal stability and well electron-injection property.

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  • 收稿日期:  2007-08-27
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