Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

Citation: Jin-long Pan, Zhen Li, Li-fen Zhang, Zhen-ping Cheng, Xiu-lin Zhu. Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1010-1018. doi: 10.1007/s10118-014-1481-2 shu

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

1.
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21174096, 21274100 and 21234005), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20103201110005), the Project of International Cooperation of the Ministry of Science and Technology of China (No. 2011DFA50530), and the project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要: Atom transfer radical polymerization of styrene (St) and methyl methacrylate (MMA) in bulk and in different solvents using activators generated by electron transfer (AGET ATRP) were investigated in the presence of a limited amount of air using FeCl36H2O as the catalyst, ascorbic acid sodium salt (AsAc-Na) as the reducing agent, and a cheap and commercially available tetrabutylammonium bromide (TBABr) as the ligand. It was found that polymerization in THF resulted in shorter induction period than that in bulk and in toluene for AGET ATRP of St, while referring to AGET ATRP of MMA, polymerization in THF showed three advantages compared with that in bulk and toluene: 1) shortening the induction period, 2) enhancing the polymerization rate and 3) having better controllability. The living features of the obtained polymers were verified by chain end analysis and chain-extension experiments.

关键词:

Atom transfer radical polymerization (ATRP)
/ AGET ATRP
/ Iron catalyst
/ Kinetics (polym)

English

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

1.
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
Received Date: 14 November 2013
Revised Date: 14 December 2013
Available Online: 05 August 2014
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21174096, 21274100 and 21234005), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20103201110005), the Project of International Cooperation of the Ministry of Science and Technology of China (No. 2011DFA50530), and the project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Abstract: Atom transfer radical polymerization of styrene (St) and methyl methacrylate (MMA) in bulk and in different solvents using activators generated by electron transfer (AGET ATRP) were investigated in the presence of a limited amount of air using FeCl36H2O as the catalyst, ascorbic acid sodium salt (AsAc-Na) as the reducing agent, and a cheap and commercially available tetrabutylammonium bromide (TBABr) as the ligand. It was found that polymerization in THF resulted in shorter induction period than that in bulk and in toluene for AGET ATRP of St, while referring to AGET ATRP of MMA, polymerization in THF showed three advantages compared with that in bulk and toluene: 1) shortening the induction period, 2) enhancing the polymerization rate and 3) having better controllability. The living features of the obtained polymers were verified by chain end analysis and chain-extension experiments.

Key words:

Atom transfer radical polymerization (ATRP)
/ AGET ATRP
/ Iron catalyst
/ Kinetics (polym)

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

English

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

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Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

English

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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