引用本文:
Bao Zhong CAI, Lun Tzu LIU, Ru Yu CHEN. STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS[J]. Chinese Chemical Letters,
1991, 2(7): 531-534.
Citation: Bao Zhong CAI, Lun Tzu LIU, Ru Yu CHEN. STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS[J]. Chinese Chemical Letters, 1991, 2(7): 531-534.
Citation: Bao Zhong CAI, Lun Tzu LIU, Ru Yu CHEN. STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS[J]. Chinese Chemical Letters, 1991, 2(7): 531-534.
STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS
摘要:
Rapid addition of alcohols to 1, 2, 3-diazaphosphole 1 easily gave tricoordinated phosphorus compounds, which were sulfurized to tetracoordinated phosphorus compounds.When ethylene glycol and aminoethanol were used separately to react with 1, the tricoordinated phosphorus compounds which formed, rearranged to pentacoordinated phosphorus compounds and the substituents at N2 affected the rearrangement significantly
English
STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS
Abstract:
Rapid addition of alcohols to 1, 2, 3-diazaphosphole 1 easily gave tricoordinated phosphorus compounds, which were sulfurized to tetracoordinated phosphorus compounds.When ethylene glycol and aminoethanol were used separately to react with 1, the tricoordinated phosphorus compounds which formed, rearranged to pentacoordinated phosphorus compounds and the substituents at N2 affected the rearrangement significantly
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