引用本文:
Si Yu MA, Xiao Yuan FU. THE REGIOSPECIFICITY OF INTRAMOLECULAR N-3-BUTENYL NITRONE CYCLOADDITION[J]. Chinese Chemical Letters,
1991, 2(7): 535-536.
Citation: Si Yu MA, Xiao Yuan FU. THE REGIOSPECIFICITY OF INTRAMOLECULAR N-3-BUTENYL NITRONE CYCLOADDITION[J]. Chinese Chemical Letters, 1991, 2(7): 535-536.
Citation: Si Yu MA, Xiao Yuan FU. THE REGIOSPECIFICITY OF INTRAMOLECULAR N-3-BUTENYL NITRONE CYCLOADDITION[J]. Chinese Chemical Letters, 1991, 2(7): 535-536.
THE REGIOSPECIFICITY OF INTRAMOLECULAR N-3-BUTENYL NITRONE CYCLOADDITION
摘要:
The reaction mechanism of the intramolecular cycloaddition of N-3-butenyl nitrone has been investigated theoretically by using AM1 MO method and transition state theory.There are two parallel reactions leading to two different regioisomers.The ratio of the rate constants of these two reactions was calculated to be 124.1(at 383.75 K).The obtained results can be used to explain the high regiospecificity of the reaction product.
English
THE REGIOSPECIFICITY OF INTRAMOLECULAR N-3-BUTENYL NITRONE CYCLOADDITION
Abstract:
The reaction mechanism of the intramolecular cycloaddition of N-3-butenyl nitrone has been investigated theoretically by using AM1 MO method and transition state theory.There are two parallel reactions leading to two different regioisomers.The ratio of the rate constants of these two reactions was calculated to be 124.1(at 383.75 K).The obtained results can be used to explain the high regiospecificity of the reaction product.
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