引用本文:
Zhan Zhu LIU, Ye WANG, Shi Zhi CHEN. Construction of the Skeleton of Phthalascidin, Mechanism of the Formation of the Key Tricyclic Lactam Intermediate[J]. Chinese Chemical Letters,
2002, 13(8): 701-704.
Citation: Zhan Zhu LIU, Ye WANG, Shi Zhi CHEN. Construction of the Skeleton of Phthalascidin, Mechanism of the Formation of the Key Tricyclic Lactam Intermediate[J]. Chinese Chemical Letters, 2002, 13(8): 701-704.
Citation: Zhan Zhu LIU, Ye WANG, Shi Zhi CHEN. Construction of the Skeleton of Phthalascidin, Mechanism of the Formation of the Key Tricyclic Lactam Intermediate[J]. Chinese Chemical Letters, 2002, 13(8): 701-704.
Construction of the Skeleton of Phthalascidin, Mechanism of the Formation of the Key Tricyclic Lactam Intermediate
摘要:
The mechanism of the formation of a key tricyclic lactam intermediate 3 was studied. It was found that the E-form compound 3 was transformed from the Z-form compound 4. The formation of 4 was a kinetically controlled process while the formation of 3 was a thermodynamically favorable one. A possible mechanism was given in this paper.
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关键词:
- Lactam
- / phthalascidin
- / mechanism
- / Et-743
English
Construction of the Skeleton of Phthalascidin, Mechanism of the Formation of the Key Tricyclic Lactam Intermediate
Abstract:
The mechanism of the formation of a key tricyclic lactam intermediate 3 was studied. It was found that the E-form compound 3 was transformed from the Z-form compound 4. The formation of 4 was a kinetically controlled process while the formation of 3 was a thermodynamically favorable one. A possible mechanism was given in this paper.
-
Key words:
- Lactam
- / phthalascidin
- / mechanism
- / Et-743
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