MORPHOLOGY AND MECHANICAL PROPERTIES OF POLYPROPYLENE WITH in situ FORMED POLYAMIDE-6 FIBRILS

Dong Liang Qin Zhang Rong-ni Du Qiang Fu

Citation:  Dong Liang, Qin Zhang, Rong-ni Du, Qiang Fu. MORPHOLOGY AND MECHANICAL PROPERTIES OF POLYPROPYLENE WITH in situ FORMED POLYAMIDE-6 FIBRILS[J]. Chinese Journal of Polymer Science, 2007, 25(6): 599-607. shu

MORPHOLOGY AND MECHANICAL PROPERTIES OF POLYPROPYLENE WITH in situ FORMED POLYAMIDE-6 FIBRILS

摘要: in situ Fibril formation of polyamide-6 (PA6) in isotropic polypropylene (iPP) was first fabricated using a slit die extrusion and hot stretching process. Then the prepared materials were subjected to injection molding in the temperature range higher than the melting temperature of iPP but lower than that of PA6. The obtained injection-molded samples were characterized via scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and two-dimensional wide-angle X-ray scattering (2D-WAXS). Mechanical properties were also investigated. The SEM result shows that the optimum fibril formation could be only achieved in the range of 20 wt% to 30 wt% of PA6 content for the studied system. The fibril morphology changes along the sample thickness in the injection-molded bars. The fibril morphology in the skin layer was better than that in the core layer. 2D-WAXS results showed that the orientation of PP decreased with the increase of PA6 content, which indicated that the orientation of PP was confined by PA6 fibrils. Combined consideration of mechanical properties and morphology indicates that only PP/PA6 composites with 20 wt% of PA6 content show better properties because of the better fibril morphology and PP chain orientation.

English


  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  810
  • HTML全文浏览量:  4
文章相关
  • 发布日期:  2007-11-20
  • 收稿日期:  2006-10-17
  • 修回日期:  2006-12-31
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章