Synthesis and Crystal Structure of N-(Biphenyl-2-thiocarbamoyl)-4-(1,3-dichlorophenyl) Carboxamide

AAMER SAEED ULRICH FLÖRKE

Citation:  AAMER SAEED, ULRICH FLÖRKE. Synthesis and Crystal Structure of N-(Biphenyl-2-thiocarbamoyl)-4-(1,3-dichlorophenyl) Carboxamide[J]. Chinese Journal of Structural Chemistry, 2015, 34(6): 853-857. doi: 10.14102/j.cnki.0254-5861.2010-1479 shu

Synthesis and Crystal Structure of N-(Biphenyl-2-thiocarbamoyl)-4-(1,3-dichlorophenyl) Carboxamide

摘要: The synthesis of the title molecule was achieved by the reaction of 2,4-dichlorobenzoyl chloride with potassium thiocyanate in 1:1 molar ratio in dry acetonitrile to afford the corresponding isothiocyante in situ followed by the treatment with 2-aminobiphenyl. The structure of the target compound was established by elemental analysis, FTIR, 1H, 13C NMR and mass spectroscopy and unequivocally confirmed by the crystallographic data. The title compound crystallizes in the monoclinic space group P21/n with a=13.356(2), b=7.0761(11), c=20.539(3) Å, β=105.723(4)°, V=1868.5(5) Å3 and Z=4.

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  • 收稿日期:  2014-04-18
  • 网络出版日期:  2015-03-30
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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